Abstract Discovered in 2005, cyclic (alkyl)(amino) carbenes (CAACs) are among the most
nucleophilic (σ donating) and also electrophilic (π‐accepting) stable carbenes known to …

Discovered as organometallic curiosities in the 1970s, carbene radicals have become a
staple in modern-day homogeneous catalysis. Carbene radicals exhibit nucleophilic radical …

Conspectus N-Heterocyclic carbenes (NHCs) are known to stabilize some metal atoms in
different oxidation states mostly by their strong σ-donation. After the successful syntheses of …

Ein Kennzeichen der seit 2005 bekannten cyclischen Alkylaminocarbene (CAACs) ist ihre
ausgeprägte Nucleophilie (σ‐Donor) und zugleich Elektrophile (π‐Akzeptor). Diese …

Isolation of cyclic (alkyl) amino carbenes (cAACs) in 2005 has been a major achievement in
the field of stable carbenes due to their better electronic properties. cAACs and bicyclic …

One-electron oxidation of palladium (0) and platinum (0) bis (phosphine) complexes
enables isolation of a homologous series of linear d9 metalloradicals of the form [M (PR3) …

We present a substantial update to the PyFrag 2008 program, which was originally designed
to perform a fragment‐based activation strain analysis along a provided potential energy …

The first synthesis of cyclic (alkyl)(amino) carbenes (cAACs) was reported in 2005, and since
then this class of carbenes has been on a victory tour in main‐group‐element and transition …

Abstract A cyclic (alkyl)(amino) carbene (CAAC) was found to undergo unprecedented
rearrangements and transformations of its core structure in the presence of Group 1 and 2 …

Palladium (II) and platinum (II) complexes featuring metalla-N-heterocyclic carbenes (7–12)
were synthesised via metal-mediated coupling between equimolar cis-[MCl2 (CNR) 2](R= 2 …