A test of the universality principle: The solubility of metal salts and oxides in isobutyric acid+ water near its consolute point

X Wang, PR Norris, J Mote, R Mauro… - Journal of Molecular …, 2023 - Elsevier
A mixture of isobutyric acid+ water has a critical point of solution at a composition of 38.8
mass% isobutyric acid and a temperature near 300 K. Under these conditions, the pH= 2 …

Test of the universality Principle: The solubility of organic solids in binary liquid mixtures having a critical point of solution

PR Norris, X Wang, JK Baird - Journal of Molecular Liquids, 2024 - Elsevier
We have determined the temperature dependence of the solubility of both chemically inert
and chemically reactive organic solids in a variety of binary liquid mixtures having a critical …

Phase rule classification of physical and chemical critical effects in liquid mixtures

JK Baird, X Wang, JR Lang, P Norris - Chemical Physics Letters, 2019 - Elsevier
The isobaric heat capacity and the coefficient of thermal expansion of a binary liquid mixture
with a critical point of solution diverge as functions of temperature in the critical region. When …

Quenching of critical opalescence in binary liquid mixtures

X Wang, CM Lyons, JK Baird - Journal of Molecular Liquids, 2023 - Elsevier
Critical phenomena occur in pure fluids, superfluids, and in binary liquid mixtures having a
miscibility gap ending in a critical point of solution. Of the three, only the binary liquid …

Phase rule and the universality of critical phenomena in chemically reacting liquid mixtures

JK Baird, JR Lang, X Wang, A Mukherjee… - The Journal of …, 2019 - ACS Publications
Critical effects have been reported in the case of chemical equilibria, in which the solvent is
a binary liquid mixture having a critical point of solution. At atmospheric pressure and for …

The universality of solubility divergence effects in multicomponent liquid mixtures

PR Norris - 2022 - search.proquest.com
Critical point effects have been observed in pure fluids, ferromagnets, substitutional alloys,
and in binary liquid mixtures having a miscibility gap. That these systems are disparate …

Phase rule and isomorphism principle analysis of critical phenomena in multicomponent systems

X Wang - 2022 - search.proquest.com
This dissertation investigates critical phenomena in the liquid mixture near its liquid-liquid
critical solution temperature, especially for critical effects on solubilities and turbidities …

Kinetics of two redox reactions in 2‐butoxyethanol and water near its critical point of solution

Z Du, S Duan, M Ma, X Xu, Z Li… - International Journal of …, 2019 - Wiley Online Library
The rate constants of two redox reactions and in the critical solution of 2‐butoxyethanol and
water have been measured by using the UV spectrophotometry at the initial reaction stage. It …

[PDF][PDF] Critical Effect of Barium Solubility in a Binary Liquid Mixture

JS Mote - 2022 - louis.uah.edu
There are more than 1000 pairs of liquid mixtures that exhibit a critical point of solution at
atmospheric pressure. These mixtures can be used as solvents for chemical reactions and …

[图书][B] Solid-liquid phase equilibria near a critical point of solution

X Wang - 2018 - search.proquest.com
Three experiments, including the dissolution of barium chromate in the isobutyric acid (IBA)+
water and the dissolution of lead sulfate and lead iodide in the IBA+ water, were performed …