Organoboron-based multiple-resonance emitters: synthesis, structure–property correlations, and prospects

M Mamada, M Hayakawa, J Ochi… - Chemical Society …, 2024 - pubs.rsc.org
Boron-based multiple-resonance (MR) emitters exhibit the advantages of narrowband
emission, high absolute photoluminescence quantum yield, thermally activated delayed …

Structurally constrained boron-, nitrogen-, silicon-, and phosphorus-centered polycyclic π-conjugated systems

M Hirai, N Tanaka, M Sakai, S Yamaguchi - Chemical reviews, 2019 - ACS Publications
Incorporation of main group elements into the π-conjugated frameworks is a sophisticated
strategy to alter the fundamental nature of the parent conjugated π-systems, giving rise to …

Discriminating Active B N Sites in Coralloidal B, N Dual‐Doped Carbon Nano‐Bundles for Boosted Zn‐Ion Storage Capability

X Chen, P Ye, H Wang, H Huang… - Advanced Functional …, 2023 - Wiley Online Library
Dual doping of boron (B) and nitrogen (N) provides an effective strategy to tailor chemical
properties and electron distributions in the carbon plane, as well as customize the energy …

Near-infrared-absorbing B–N lewis pair-functionalized anthracenes: electronic structure tuning, conformational isomerism, and applications in photothermal cancer …

K Liu, Z Jiang, RA Lalancette, X Tang… - Journal of the American …, 2022 - ACS Publications
B–N-fused dianthracenylpyrazine derivatives are synthesized to generate new low gap
chromophores. Photophysical and electrochemical, crystal packing, and theoretical studies …

Phenalenyl radical: Smallest polycyclic odd alternant hydrocarbon present in the graphene sheet

J Ahmed, SK Mandal - Chemical Reviews, 2022 - ACS Publications
Phenalenyl, a zigzag-edged odd alternant hydrocarbon unit can be found in the graphene
nanosheet. Hückel molecular orbital calculations indicate the presence of a nonbonding …

Recent developments in and perspectives on three-coordinate boron materials: a bright future

L Ji, S Griesbeck, TB Marder - Chemical Science, 2017 - pubs.rsc.org
The empty pz-orbital of a three-coordinate organoboron compound leads to its electron-
deficient properties, which make it an excellent π-acceptor in conjugated organic …

Boron: its role in energy‐related processes and applications

Z Huang, S Wang, RD Dewhurst… - Angewandte Chemie …, 2020 - Wiley Online Library
Boron's unique position in the Periodic Table, that is, at the apex of the line separating
metals and nonmetals, makes it highly versatile in chemical reactions and applications …

The state of the art in azaborine chemistry: new synthetic methods and applications

ZX Giustra, SY Liu - Journal of the American Chemical Society, 2018 - ACS Publications
Boron–nitrogen heteroarenes hold great promise for practical application in many areas of
chemistry. Enduring interest in realizing this potential has in turn driven perennial innovation …

Synthetic Tailoring of graphene nanostructures with zigzag‐edged topologies: progress and perspectives

J Liu, X Feng - Angewandte Chemie International Edition, 2020 - Wiley Online Library
Experimental and theoretical investigations have revealed that the chemical and physical
properties of graphene are crucially determined by their topological structures. Therefore …

Constructing interfacial boron‐nitrogen moieties in turbostratic carbon for electrochemical hydrogen peroxide production

Z Tian, Q Zhang, L Thomsen, N Gao, J Pan… - Angewandte …, 2022 - Wiley Online Library
The electrochemical oxygen reduction reaction (ORR) provides a green route for
decentralized H2O2 synthesis, where a structure–selectivity relationship is pivotal for the …