Expanded theory of H-and J-molecular aggregates: the effects of vibronic coupling and intermolecular charge transfer

NJ Hestand, FC Spano - Chemical reviews, 2018 - ACS Publications
The electronic excited states of molecular aggregates and their photophysical signatures
have long fascinated spectroscopists and theoreticians alike since the advent of Frenkel …

Pathways to increase the dissymmetry in the interaction of chiral light and chiral molecules

JL Greenfield, J Wade, JR Brandt, X Shi, TJ Penfold… - Chemical …, 2021 - pubs.rsc.org
The dissymmetric interaction between circularly polarised (CP) light and chiral molecules is
central to a range of areas, from spectroscopy and imaging to next-generation photonic …

Accelerating symmetry-breaking charge separation in a perylenediimide trimer through a vibronically coherent dimer intermediate

C Lin, T Kim, JD Schultz, RM Young… - Nature chemistry, 2022 - nature.com
Understanding the photophysics and photochemistry of molecular π-stacked chromophores
is important for utilizing them as functional photonic materials. However, these investigations …

Organic optoelectronic materials: mechanisms and applications

O Ostroverkhova - Chemical reviews, 2016 - ACS Publications
Organic (opto) electronic materials have received considerable attention due to their
applications in thin-film-transistors, light-emitting diodes, solar cells, sensors, photorefractive …

Perylene bisimide dye assemblies as archetype functional supramolecular materials

F Würthner, CR Saha-Möller, B Fimmel… - Chemical …, 2016 - ACS Publications
When many of the currently largest chemical companies were founded about 150 years ago,
textile dyes constituted their first products. Interestingly, while most of the utilized colorants …

Null exciton-coupled chromophoric dimer exhibits symmetry-breaking charge separation

E Sebastian, M Hariharan - Journal of the American Chemical …, 2021 - ACS Publications
A comprehensive understanding of the structure–property relationships in
multichromophoric architectures has pushed the limits for developing robust photosynthetic …

Exciton–vibrational coupling in the dynamics and spectroscopy of Frenkel excitons in molecular aggregates

M Schröter, SD Ivanov, J Schulze, SP Polyutov, Y Yan… - Physics Reports, 2015 - Elsevier
The influence of exciton–vibrational coupling on the optical and transport properties of
molecular aggregates is an old problem that gained renewed interest in recent years. On the …

Discrete π-stacks of perylene bisimide dyes within folda-dimers: insight into long-and short-range exciton coupling

C Kaufmann, D Bialas, M Stolte… - Journal of the American …, 2018 - ACS Publications
Four well-defined π-stacks of perylene bisimide (PBI) dyes were obtained in solution by
covalent linkage of two chromophores with spacer units of different length and sterical …

Direct observation of a charge-transfer state preceding high-yield singlet fission in terrylenediimide thin films

EA Margulies, JL Logsdon, CE Miller… - Journal of the …, 2017 - ACS Publications
Singlet exciton fission (SF) in organic chromophore assemblies results in the conversion of
one singlet exciton (S1) into two triplet excitons (T1), provided that the overall process is …

Direct observation of ultrafast coherent exciton dynamics in helical π-stacks of self-assembled perylene bisimides

J Sung, P Kim, B Fimmel, F Würthner, D Kim - Nature communications, 2015 - nature.com
Ever since the discovery of dye self-assemblies in nature, there have been tremendous
efforts to exploit biomimetic supramolecular assemblies for tailored artificial photon …