Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

Unraveling structure and dynamics in porous frameworks via advanced in situ characterization techniques

V Bon, E Brunner, A Pöppl… - Advanced Functional …, 2020 - Wiley Online Library
Dynamic metal–organic frameworks (MOFs) represent a subgroup of frameworks featuring
unique performance, as they are capable of adapting their pore size and/or the orientation of …

Trends in Solid Adsorbent Materials Development for CO2 Capture

M Pardakhti, T Jafari, Z Tobin, B Dutta… - … applied materials & …, 2019 - ACS Publications
A recent report from the United Nations has warned about the excessive CO2 emissions and
the necessity of making efforts to keep the increase in global temperature below 2° C …

Quantum Informed Machine-Learning Potentials for Molecular Dynamics Simulations of CO2's Chemisorption and Diffusion in Mg-MOF-74

B Zheng, FL Oliveira, R Neumann Barros Ferreira… - ACS …, 2023 - ACS Publications
Among various porous solids for gas separation and purification, metal-organic frameworks
(MOFs) are promising materials that potentially combine high CO2 uptake and CO2/N2 …

Low-concentration CO2 capture system with liquid-like adsorbent based on monoethanolamine for low energy consumption

JW Lee, H Ahn, S Kim, YT Kang - Journal of Cleaner Production, 2023 - Elsevier
Direct air capture (DAC) of atmospheric CO 2 is becoming ever more important for a carbon
neutral society. To achieve this, it is critical to reduce the energy consumption of DAC …

Isolated iron sites embedded in graphitic carbon nitride (g-C3N4) for efficient oxidative desulfurization

G Lei, W Zhao, L Shen, S Liang, C Au… - Applied Catalysis B …, 2020 - Elsevier
Iron-based catalysts are promising for the catalytic oxidation of H 2 S owing to their non-
toxicity, abundance, and high conversion efficiency. However, their industrial applications …

Understanding metal–organic framework nucleation from a solution with evolving graphs

L Kollias, R Rousseau, VA Glezakou… - Journal of the …, 2022 - ACS Publications
A mechanistic understanding of metal–organic framework (MOF) synthesis and scale-up
remains underexplored due to the complex nature of the interactions of their building blocks …

Metal–organic frameworks as O 2-selective adsorbents for air separations

DE Jaramillo, A Jaffe, BER Snyder, A Smith, E Taw… - Chemical …, 2022 - pubs.rsc.org
Oxygen is a critical gas in numerous industries and is produced globally on a gigatonne
scale, primarily through energy-intensive cryogenic distillation of air. The realization of large …

A multifunctional Zr (iv)-based metal–organic framework for highly efficient elimination of Cr (vi) from the aqueous phase

J Liu, Y Ye, X Sun, B Liu, G Li, Z Liang… - Journal of materials …, 2019 - pubs.rsc.org
A highly stable luminescent Zr (IV)-MOF,[Zr6O4 (OH) 8 (H2O) 4 (TCPP) 4]· 9DMF· 3.5 H2O
(JLU-MOF60, H4TCPP= 2, 3, 5, 6-tetrakis (4-carboxyphenyl) pyrazine, DMF= N, N …

Simultaneous improvement of mechanical and fire-safety properties of polymer composites with phosphonate-loaded MOF additives

XL Qi, DD Zhou, J Zhang, S Hu… - … applied materials & …, 2019 - ACS Publications
Flame-retardant (FR) additives are commonly used to improve the fire safety of synthetic
polymers, which are widely employed in manufactured consumer goods. Incorporation of an …