A review of the retention mechanisms of redox-sensitive radionuclides in multi-barrier systems

B Ma, L Charlet, A Fernandez-Martinez, M Kang… - Applied …, 2019 - Elsevier
The deep geological disposal concept is widely accepted by the scientific community for the
storage of high activity level nuclear waste. It uses a multi-barrier system to isolate …

[PDF][PDF] Modeling specific pH dependent sorption of divalent metals on montmorillonite surfaces. A review of pitfalls, recent achievements and current challenges

C Tournassat, S Grangeon, P Leroy… - American Journal of …, 2013 - ajsonline.org
Within the context of the clay barrier concept for underground nuclear waste disposal,
montmorillonite and bentonite have been widely used as reference materials for sorption. In …

Sorption of Ni (II) on GMZ bentonite: effects of pH, ionic strength, foreign ions, humic acid and temperature

S Yang, J Li, Y Lu, Y Chen, X Wang - Applied Radiation and Isotopes, 2009 - Elsevier
Bentonite has been widely studied in nuclear waste management because of its special
physicochemical properties. In this work, the sorption of Ni (II) from aqueous solution onto …

Modeling the acid–base properties of montmorillonite edge surfaces

C Tournassat, JA Davis, C Chiaberge… - Environmental …, 2016 - ACS Publications
The surface reactivity of clay minerals remains challenging to characterize because of a
duality of adsorption surfaces and mechanisms that does not exist in the case of simple …

Diffusion-driven transport in clayrock formations

S Altmann, C Tournassat, F Goutelard, JC Parneix… - Applied …, 2012 - Elsevier
Clay mineral-rich sedimentary formations are currently under investigation to evaluate their
potential use as host formations for installation of deep underground disposal facilities for …

Uranium retention in a Callovo-Oxfordian clay rock formation: From laboratory-based models to in natura conditions

G Montavon, S Ribet, YH Loni, F Maia, C Bailly… - Chemosphere, 2022 - Elsevier
For the performance assessment of radioactive waste disposal, it is critical to predict the
mobility of radionuclides in the geological barrier that hosts it. A key challenge consists of …

Ionic transport in nano-porous clays with consideration of electrostatic effects

C Tournassat, CI Steefel - Reviews in Mineralogy and …, 2015 - pubs.geoscienceworld.org
The mineralogical and chemical properties of clays have been the subject of longstanding
study in the research community—in fact, entire journals are devoted to the topic. In the field …

Cs+ sorption onto Kutch clays: Influence of competing ions

AS Semenkova, MV Evsiunina, PK Verma… - Applied Clay …, 2018 - Elsevier
The sorption of Cs+ onto raw Kutch clay (India) over a wide range of concentrations and pH
levels was studied and compared with its sorption onto the well-studied FEBEX clay (Spain) …

Adsorptive performance of un-calcined sodium exchanged and acid modified montmorillonite for Ni2+ removal: Equilibrium, kinetics, thermodynamics and …

CO Ijagbemi, MH Baek, DS Kim - Journal of Hazardous Materials, 2010 - Elsevier
The efficacy of un-calcined sodium exchanged (Na-MMT) and acid modified montmorillonite
(A-MMT) has been investigated for adsorptive removal of Ni2+ from aqueous solution …

Effect of pH and ionic strength on sorption of Eu (III) to MX-80 bentonite: batch and XAFS study

GD Sheng, DD Shao, QH Fan, D Xu, YX Chen… - rca-Radiochimica …, 2009 - degruyter.com
Sorption of radionuclides on MX-80 bentonite has been studied extensively because of its
high sorption capacity and low penetrability. Herein, MX-80 bentonite was characterized by …