Recent progress in the science of complex coacervation

CE Sing, SL Perry - Soft Matter, 2020 - pubs.rsc.org
Complex coacervation is an associative, liquid–liquid phase separation that can occur in
solutions of oppositely-charged macromolecular species, such as proteins, polymers, and …

The entropy-controlled strategy in self-assembling systems

X Zhang, X Dai, L Gao, D Xu, H Wan, Y Wang… - Chemical Society …, 2023 - pubs.rsc.org
Self-assembly of various building blocks has been considered as a powerful approach to
generate novel materials with tailorable structures and optimal properties. Understanding …

Modeling and simulations of polymers: a roadmap

TE Gartner III, A Jayaraman - Macromolecules, 2019 - ACS Publications
Molecular modeling and simulations are invaluable tools for the polymer science and
engineering community. These computational approaches enable predictions and provide …

Nanocomposites with polymer grafted nanoparticles

SK Kumar, N Jouault, B Benicewicz, T Neely - Macromolecules, 2013 - ACS Publications
A recurring challenge in the field of nanocomposites is to control the spatial distribution of
nanoparticles (NPs) in a polymer matrix. This issue is of critical importance since it is now …

Toward functional nanocomposites: taking the best of nanoparticles, polymers, and small molecules

J Kao, K Thorkelsson, P Bai, BJ Rancatore… - Chemical Society …, 2013 - pubs.rsc.org
Nanocomposites, composed of organic and inorganic building blocks, can combine the
properties from the parent constituents and generate new properties to meet current and …

Nanoparticle dispersion and aggregation in polymer nanocomposites: insights from molecular dynamics simulation

J Liu, Y Gao, D Cao, L Zhang, Z Guo - Langmuir, 2011 - ACS Publications
It is a great challenge to fully understand the microscopic dispersion and aggregation of
nanoparticles (NPs) in polymer nanocomposites (PNCs) through experimental techniques …

Perspective: Outstanding theoretical questions in polymer-nanoparticle hybrids

SK Kumar, V Ganesan, RA Riggleman - The Journal of chemical …, 2017 - pubs.aip.org
This topical review discusses the theoretical progress made in the field of polymer
nanocomposites, ie, hybrid materials created by mixing (typically inorganic) nanoparticles …

Theory and simulation studies of effective interactions, phase behavior and morphology in polymer nanocomposites

V Ganesan, A Jayaraman - Soft Matter, 2014 - pubs.rsc.org
Polymer nanocomposites are a class of materials that consist of a polymer matrix filled with
inorganic/organic nanoscale additives that enhance the inherent macroscopic (mechanical …

Materials design of highly branched bottlebrush polymers at the intersection of modeling, synthesis, processing, and characterization

T Pan, S Dutta, Y Kamble, BB Patel… - Chemistry of …, 2022 - ACS Publications
Highly branched “bottlebrush” polymers are a class of macromolecules characterized by
side chains that are densely grafted from a backbone that is typically linear. Their unique …

Prism-based theory of complex coacervation: Excluded volume versus chain correlation

SL Perry, CE Sing - Macromolecules, 2015 - ACS Publications
Aqueous solutions of oppositely charged polyelectrolytes can undergo liquid–liquid phase
separation into materials known as complex coacervates. These coacervates have been a …