Sulfonyl fluorides as targets and substrates in the development of new synthetic methods

TSB Lou, MC Willis - Nature Reviews Chemistry, 2022 - nature.com
The advent of sulfur (vi)-fluoride exchange (SuFEx) processes as transformations with click-
like reactivity has invigorated research into electrophilic species featuring a sulfur–fluorine …

The growing applications of SuFEx click chemistry

AS Barrow, CJ Smedley, Q Zheng, S Li… - Chemical Society …, 2019 - pubs.rsc.org
SuFEx (Sulfur Fluoride Exchange) is a modular, next generation family of click reactions,
geared towards the rapid and reliable assembly of functional molecules. This review …

Radical Hydro‐Fluorosulfonylation of Unactivated Alkenes and Alkynes

P Wang, H Zhang, M Zhao, S Ji, L Lin… - Angewandte Chemie …, 2022 - Wiley Online Library
Recently, radical fluorosulfonylation is emerging as an appealing approach for the synthesis
of sulfonyl fluorides, which are highly in demand in various disciplines, particularly in …

The emerging applications of sulfur (VI) fluorides in catalysis

C Lee, AJ Cook, JE Elisabeth, NC Friede… - ACS …, 2021 - ACS Publications
The past decade has witnessed remarkable growth of catalytic transformations in organic
sulfur (VI) fluoride chemistry. This Perspective concentrates exclusively on foundational …

[HTML][HTML] Photoredox catalytic radical fluorosulfonylation of olefins enabled by a bench-stable redox-active fluorosulfonyl radical precursor

P Wang, H Zhang, X Nie, T Xu, S Liao - Nature Communications, 2022 - nature.com
Sulfonyl fluorides have attracted considerable and growing research interests from various
disciplines, which raises a high demand for novel and effective methods to access this class …

Electrochemical Oxo‐Fluorosulfonylation of Alkynes under Air: Facile Access to β‐Keto Sulfonyl Fluorides

D Chen, X Nie, Q Feng, Y Zhang… - Angewandte Chemie …, 2021 - Wiley Online Library
Radical fluorosulfonylation is emerging as an appealing approach for the synthesis of
sulfonyl fluorides, which have widespread applications in many fields, in particular in the …

Emerging building blocks for medicinal chemistry: recent synthetic advances

OO Grygorenko, DM Volochnyuk… - European Journal of …, 2021 - Wiley Online Library
Current medicinal chemistry relies heavily on the quality of building blocks, ie reagents used
to introduce chemical diversity into the target molecules. The last decade witnessed an …

Introducing A New Class of Sulfonyl Fluoride Hubs via Radical Chloro‐Fluorosulfonylation of Alkynes

X Nie, T Xu, Y Hong, H Zhang, C Mao… - Angewandte Chemie …, 2021 - Wiley Online Library
Sulfonyl fluorides have widespread applications in many important fields, including ligation
chemistry, chemical biology, and drug discovery. Therefore, new methods to increase the …

Radical fluorosulfonylation: accessing alkenyl sulfonyl fluorides from alkenes

X Nie, T Xu, J Song, A Devaraj, B Zhang… - Angewandte …, 2021 - Wiley Online Library
Sulfonyl fluorides have widespread applications in many fields. In particular, their unique
biological activity has drawn considerable research interest in the context of chemical …

Linkage chemistry of S (VI) fluorides

D Zeng, WP Deng, X Jiang - Chemistry–A European Journal, 2023 - Wiley Online Library
Sulfur (VI)‐fluoride exchange linkage as a next generation of click chemistry was introduced
by Sharpless and coworkers in 2014. Distinguished from CuAAC, the SuFEx reaction …