Metal Centers as Nucleophiles: Oxymoron of Halogen Bond‐Involving Crystal Engineering
DM Ivanov, NA Bokach… - … –A European Journal, 2022 - Wiley Online Library
This review highlights recent studies discovering unconventional halogen bonding (HaB)
that involves positively charged metal centers. These centers provide their filled d‐orbitals …
that involves positively charged metal centers. These centers provide their filled d‐orbitals …
Efficient and durable Au alloyed Pd single-atom catalyst for the Ullmann reaction of aryl chlorides in water
L Zhang, A Wang, JT Miller, X Liu, X Yang… - ACS …, 2014 - ACS Publications
Ion exchange resin supported Au alloyed Pd single atoms have been explored to serve as
an effective and robust catalyst for the Ullmann reaction of aryl halides under mild conditions …
an effective and robust catalyst for the Ullmann reaction of aryl halides under mild conditions …
Halogen Bonding Involving Gold Nucleophiles in Different Oxidation States
IS Aliyarova, EY Tupikina, NS Soldatova… - Inorganic …, 2022 - ACS Publications
A single-crystal X-ray diffraction (XRD) study of diaryliodonium tetrachloroaurates (or, in the
recent terminology, tetrachloridoaurates),[(p-XC6H4) 2I][AuCl4](X= Cl, 1; Br, 2), was …
recent terminology, tetrachloridoaurates),[(p-XC6H4) 2I][AuCl4](X= Cl, 1; Br, 2), was …
Oxidative coupling of Organoboron compounds
An increasing number of boron‐mediated reactions have become leading synthetic tools in
organic chemistry. The transition‐metal‐catalyzed oxidative coupling reactions of aryl‐and …
organic chemistry. The transition‐metal‐catalyzed oxidative coupling reactions of aryl‐and …
Halogen bond triggered aggregation induced emission in an iodinated cyanine dye for ultra sensitive detection of Ag nanoparticles in tap water and agricultural …
MF Abdelbar, HS El-Sheshtawy, KR Shoueir… - RSC …, 2018 - pubs.rsc.org
Aggregation induced emission (AIE) has emerged as a powerful method for sensing
applications. Based on AIE triggered by halogen bond (XB) formation, an ultrasensitive and …
applications. Based on AIE triggered by halogen bond (XB) formation, an ultrasensitive and …
Studies of Nature of Uncommon Bifurcated I–I···(I–M) Metal-Involving Noncovalent Interaction in Palladium (II) and Platinum (II) Isocyanide Cocrystals
M Bulatova, DM Ivanov, JM Rautiainen… - Inorganic …, 2021 - ACS Publications
Two isostructural trans-[MI2 (CNXyl) 2]· I2 (M= Pd or Pt; CNXyl= 2, 6-dimethylphenyl
isocyanide) metallopolymeric cocrystals containing uncommon bifurcated iodine···(metal …
isocyanide) metallopolymeric cocrystals containing uncommon bifurcated iodine···(metal …
Bimetallic gold–palladium alloy nanoclusters: an effective catalyst for Ullmann coupling of chloropyridines under ambient conditions
An efficient method for the Ullmann coupling of chloropyridines catalyzed by poly (N-
vinylpyrrolidone)(PVP)-stabilized bimetallic Au–Pd alloy nanoclusters (NCs) under ambient …
vinylpyrrolidone)(PVP)-stabilized bimetallic Au–Pd alloy nanoclusters (NCs) under ambient …
Nanocatalysis: Recent advances and applications in boron chemistry
Y Zhu, NS Hosmane - Coordination Chemistry Reviews, 2015 - Elsevier
Considerable progress has been made in the application of transition metal nanoparticles
(NP)-based catalysts in boron chemistry. These offer the advantages of high efficiency and …
(NP)-based catalysts in boron chemistry. These offer the advantages of high efficiency and …
Ullmann coupling of aryl chlorides in water catalyzed by palladium nanoparticles supported on amine-grafted porous aromatic polymer
P Puthiaraj, WS Ahn - Molecular Catalysis, 2017 - Elsevier
A chemically stable porous carbonyl-incorporated aromatic polymer (CBAP-1 (EDA)) was
post-synthetically functionalized with ethylenediamine, and used as a solid support to …
post-synthetically functionalized with ethylenediamine, and used as a solid support to …
Rapid ligand-free base-accelerated copper-catalyzed homocoupling reaction of arylboronic acids
YN Cao, XC Tian, XX Chen, YX Yao, F Gao, XL Zhou - Synlett, 2017 - thieme-connect.com
A rapid, ligand-free, base-accelerated, copper-catalyzed homocoupling reaction of (het)
arylboronic acids is presented. A CuCl 2· 2H 2 O/Na 2 CO 3-based catalyst enabled the …
arylboronic acids is presented. A CuCl 2· 2H 2 O/Na 2 CO 3-based catalyst enabled the …