Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …

Considerable advances have been made in the area of C− H functionalization in the last few
decades. A number of approaches including both directed and nondirected strategies have …

Enamides, functional derivatives of enamines, play a significant role as synthetic targets.
However, the stereoselective synthesis of these molecules has posed a longstanding …

The ability to identify and transform selectively similar constitutional fragments in molecules
in a predetermined direction over all other possible directions remains a fundamental …

The direct functionalization of C− H bonds is among the most fundamental chemical
transformations in organic synthesis. However, when the innate reactivity of the substrate …

The intrinsic relationship between helicenes and circulenes is of fundamental interest and
importance in molecular engineering. Herein, electrophilic borylation of phenanthroline …

Catalytic C–H borylation is of prime topical importance, since easily available feedstock
chemicals can thereby be transformed into valuable transient functional groups in the …

The borylation of Csp3− H bonds is a challenging transformation that is typically restricted to
transition metal catalysis. Herein, we report the site‐selective metal‐free Csp3− H borylation …

C–H borylation is one of the powerful C–H bond functionalization reactions. In this context, a
metal-free C–H borylation of benzophenones using hydrazone as the traceless directing …

Amide directed C–H borylation using≥ two equiv. of BBr3 forms borenium cations
containing a R2N (R′) CO→ B (Ar) Br unit which has significant Lewis acidity at the …