This review surveys recent progress in the chemistry of polycyclic heteroaromatic molecules
with a focus on structural diversity and synthetic methodology. The article covers literature …

This Review outlines the progress in the field of synthetic expanded carbaporphyrinoids.
The evolution of this topic is demonstrated with expanded porphyrin‐inspired systems with a …

Stable and nonaromatic phenothiazinophyrins which resulted from the replacement of one
of the pyrrole rings of porphyrin with a phenothiazine unit were synthesized by condensing …

Unprecedented nonaromatic stable phenothiazine-embedded porphyrinoids were
synthesized by incorporating phenothiazine subunits into the hexaphyrin framework. The …

Porphyrinoids in which one or two pyrrole rings are replaced with polycyclic aromatic
hydrocarbons/heterocycles such as naphthalene, phenanthrene, biphenyl, bipyridine, or …

A series of new stable dibenzothiophene embedded heteroporphyrins were synthesized in 6–
7% yields by condensing 1 equiv of dibenzothiophene-based tripyrrane with 1 equiv of four …

Three novel doubly fused unsymmetrical calixdicarbahexaphyrins were synthesized by mild
acid-catalyzed (4+ 2) condensation of dicarbatetrapyrrane with dipyrroethene diol followed …

Abstract Di‐2, 7‐naphthihexaphyrin (1.1. 1.1. 1.1), a non‐aromatic carba‐analogue of the
hexaphyrin (1.1. 1.1. 1.1), incorporating two built‐in 2, 7‐naphthylene moieties was …

Expanded heteroporphyrins are a class of porphyrin macrocycles containing pyrrole,
thiophene, furan, selenophene and other heterocyclic rings that are connected to form an …

This Review discusses the recent developments in the field of synthetic chemistry of PAH–
porphyrin hybrids, emphasizing phenanthrene‐embedded carbaporphyrinoids and related …