Nitrogen-Centered Radicals in Functionalization of sp2 Systems: Generation, Reactivity, and Applications in Synthesis

C Pratley, S Fenner, JA Murphy - Chemical reviews, 2022 - ACS Publications
The chemistry of nitrogen-centered radicals (NCRs) has plentiful applications in organic
synthesis, and they continue to expand as our understanding of these reactive species …

Strategies to generate nitrogen-centered radicals that may rely on photoredox catalysis: development in reaction methodology and applications in organic synthesis

K Kwon, RT Simons, M Nandakumar… - Chemical …, 2021 - ACS Publications
For more than 70 years, nitrogen-centered radicals have been recognized as potent
synthetic intermediates. This review is a survey designed for use by chemists engaged in …

[HTML][HTML] Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium,(ii) iridium and (iii) organic photoredox agents

JD Bell, JA Murphy - Chemical Society Reviews, 2021 - pubs.rsc.org
Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …

Synthetic methods driven by the photoactivity of electron donor–acceptor complexes

GEM Crisenza, D Mazzarella… - Journal of the American …, 2020 - ACS Publications
The association of an electron-rich substrate with an electron-accepting molecule can
generate a new molecular aggregate in the ground state, called an electron donor–acceptor …

Sulfonium Salts as Acceptors in Electron Donor‐Acceptor Complexes

L van Dalsen, RE Brown… - Angewandte Chemie …, 2023 - Wiley Online Library
The photoactivation of electron donor‐acceptor complexes has emerged as a sustainable,
selective and versatile strategy for the generation of radical species. Electron donor …

Mechanistic studies in photocatalysis

L Buzzetti, GEM Crisenza… - Angewandte Chemie …, 2019 - Wiley Online Library
The fast‐moving fields of photoredox and photocatalysis have recently provided fresh
opportunities to expand the potential of synthetic organic chemistry. Advances in light …

Visible‐light photocatalysis: does it make a difference in organic synthesis?

L Marzo, SK Pagire, O Reiser… - Angewandte Chemie …, 2018 - Wiley Online Library
Visible‐light photocatalysis has evolved over the last decade into a widely used method in
organic synthesis. Photocatalytic variants have been reported for many important …

A general arene C–H functionalization strategy via electron donor–acceptor complex photoactivation

A Dewanji, L van Dalsen, JA Rossi-Ashton… - Nature Chemistry, 2023 - nature.com
The photoactivation of electron donor–acceptor complexes has emerged as a sustainable,
selective and versatile strategy for the generation of radical species. However, when it …

Organic photoredox catalysis

NA Romero, DA Nicewicz - Chemical reviews, 2016 - ACS Publications
In this review, we highlight the use of organic photoredox catalysts in a myriad of synthetic
transformations with a range of applications. This overview is arranged by catalyst class …

N–O bond activation by energy transfer photocatalysis

DS Lee, VK Soni, EJ Cho - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus A radical shift toward energy transfer photocatalysis from electron transfer
photocatalysis under visible-light photoirradiation is often due to the greener prospects of …