Nitrogen-Centered Radicals in Functionalization of sp2 Systems: Generation, Reactivity, and Applications in Synthesis
C Pratley, S Fenner, JA Murphy - Chemical reviews, 2022 - ACS Publications
The chemistry of nitrogen-centered radicals (NCRs) has plentiful applications in organic
synthesis, and they continue to expand as our understanding of these reactive species …
synthesis, and they continue to expand as our understanding of these reactive species …
Strategies to generate nitrogen-centered radicals that may rely on photoredox catalysis: development in reaction methodology and applications in organic synthesis
For more than 70 years, nitrogen-centered radicals have been recognized as potent
synthetic intermediates. This review is a survey designed for use by chemists engaged in …
synthetic intermediates. This review is a survey designed for use by chemists engaged in …
[HTML][HTML] Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium,(ii) iridium and (iii) organic photoredox agents
Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …
years, but such is the pace of progress that we will overlap very little with earlier …
Synthetic methods driven by the photoactivity of electron donor–acceptor complexes
GEM Crisenza, D Mazzarella… - Journal of the American …, 2020 - ACS Publications
The association of an electron-rich substrate with an electron-accepting molecule can
generate a new molecular aggregate in the ground state, called an electron donor–acceptor …
generate a new molecular aggregate in the ground state, called an electron donor–acceptor …
Sulfonium Salts as Acceptors in Electron Donor‐Acceptor Complexes
L van Dalsen, RE Brown… - Angewandte Chemie …, 2023 - Wiley Online Library
The photoactivation of electron donor‐acceptor complexes has emerged as a sustainable,
selective and versatile strategy for the generation of radical species. Electron donor …
selective and versatile strategy for the generation of radical species. Electron donor …
Mechanistic studies in photocatalysis
L Buzzetti, GEM Crisenza… - Angewandte Chemie …, 2019 - Wiley Online Library
The fast‐moving fields of photoredox and photocatalysis have recently provided fresh
opportunities to expand the potential of synthetic organic chemistry. Advances in light …
opportunities to expand the potential of synthetic organic chemistry. Advances in light …
Visible‐light photocatalysis: does it make a difference in organic synthesis?
Visible‐light photocatalysis has evolved over the last decade into a widely used method in
organic synthesis. Photocatalytic variants have been reported for many important …
organic synthesis. Photocatalytic variants have been reported for many important …
A general arene C–H functionalization strategy via electron donor–acceptor complex photoactivation
A Dewanji, L van Dalsen, JA Rossi-Ashton… - Nature Chemistry, 2023 - nature.com
The photoactivation of electron donor–acceptor complexes has emerged as a sustainable,
selective and versatile strategy for the generation of radical species. However, when it …
selective and versatile strategy for the generation of radical species. However, when it …
Organic photoredox catalysis
NA Romero, DA Nicewicz - Chemical reviews, 2016 - ACS Publications
In this review, we highlight the use of organic photoredox catalysts in a myriad of synthetic
transformations with a range of applications. This overview is arranged by catalyst class …
transformations with a range of applications. This overview is arranged by catalyst class …
N–O bond activation by energy transfer photocatalysis
DS Lee, VK Soni, EJ Cho - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus A radical shift toward energy transfer photocatalysis from electron transfer
photocatalysis under visible-light photoirradiation is often due to the greener prospects of …
photocatalysis under visible-light photoirradiation is often due to the greener prospects of …