Polyoxometalates (POMs) are discrete anionic metaloxygen clusters which can be regarded
as soluble oxide fragments. They exhibit a great diversity of sizes, nuclearities, and shapes …

During the past decade, research into transition-metal-substituted polyoxometalate self-
assembly has been greatly developed. This review summarizes the conventional solution …

This critical review surveys the 3d substituted magnetic polyoxotungstate (POT) molecular
compounds reported these last ten years, illustrating the huge variety of topologies that …

Polyoxometalates (POMs) are a remarkable class of inorganic compounds with enormous
structural and compositional diversity and potential applications in various fields, such as …

A tritopic, Ni‐substituted Keggin cluster,{SiW9Ni4}, assembles with rigid dicarboxylate
linkers to give rise to a set of discrete, POM2nL3n‐type structures (POM={SiW9Ni4}) with …

The chemistry of the azido-bridged coordination clusters continues to attract the intense
interest of synthetic inorganic chemists and scientists working in the interdisciplinary field of …

Abstract The {Mn 4 O 5 Ca} cluster of photosystem II is a well-known cubane-like transition-
metal (TM) cluster that plays important roles in solar energy conversion. The artificial …

The photocatalytic activity for CO 2 reduction of a series of Ni-substituted polyoxometalates
(POMs) differing in nuclearity, shape and size, has been investigated under visible light …

The design and syntheses of metal-organic cages (MOCs) based on polyoxometalates
(POMs) building blocks have attracted increasing attention due to their intriguing molecular …

The structurally new, carbon-free pentadecanuclear Fe-containing polyoxometalate, Na21
[NaFe15 (OH) 12 (PO4) 4 (A-α-SiW9O34) 4]· 85H2O (Na21-Fe 15 P 4 (SiW 9) 4), was …