Competition experiments have been performed to determine the relative reactivities of
substituted bromobenzenes, bromonaphthalenes, and 9-bromoanthracene toward i-PrMgCl …

Direct catalytic transformation of chlorosilanes into organosilicon compounds remains
challenging due to difficulty in cleaving the strong Si–Cl bond (s). We herein report the …

The main goal of this article is to the present research on the development of ketamine
derivatives. The target molecule was a fluoroderivative of ketamine, for which a multistep …

Despite the multitude of available alternatives, the Grignard coupling-based synthesis of
polycarbosilanes remains attractive, offering the benefit of easy structural design. Moreover …

Basic information on the molecular weights and structures of poly (p-phenylene) PPP, poly
(m-phenylene) PMP, poly (thiophene-2, 5-diyl) PTh, and related copolymers has been …

Organolithium compounds have been used successfully in flow chemistry since the recent
past. Most of the studies dealt with the use in halogen-lithium exchanges. So far, however …

Formation reactions of phenylmagnesium chloride and bromide in toluene in the presence
of one or two equivalents of diethyl ether or THF were investigated kinetically. Also, the …

An examination of the efficacy of combining physisorbed and chemisorbed passivation
strategies on crystalline Si has been performed. This report compares the influence of a …

Rate constants for the reactions of methylvinyldichlorosilane and tetraethoxysilane with
alkylmagnesium chlorides RMgCl (R= Et, n-Bu, i-Bu, i-Pr, s-Bu, t-Bu) in diethyl ether were …

Kinetics of reactions of ethyl-and phenylmagnesium chlorides with chlorosilanes, RMeSiCl2,
were investigated in diethyl ether under pseudo-first order conditions with a great excess of …