The transition metal-catalysed hydroboration reaction
The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …
organic molecules was initially realised several decades ago. Although this area of …
Metal-catalysed C–H bond activation and borylation
Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …
received a remarkable level of attention as a popular reaction in the synthesis of …
First-row d-block element-catalyzed carbon–boron bond formation and related processes
SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
Recent advances in asymmetric borylation by transition metal catalysis
J Hu, M Ferger, Z Shi, TB Marder - Chemical Society Reviews, 2021 - pubs.rsc.org
Chiral organoboronates have played a critical role in organic chemistry and in the
development of materials science and pharmaceuticals. Much effort has been devoted to …
development of materials science and pharmaceuticals. Much effort has been devoted to …
Photoinduced borylation for the synthesis of organoboron compounds: focus review
YM Tian, XN Guo, H Braunschweig, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …
transformations. The development of practical and convenient ways to synthesize boronate …
Methodologies and strategies for selective borylation of C–Het and C–C bonds
M Wang, Z Shi - Chemical Reviews, 2020 - ACS Publications
Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …
Nickel chain-walking catalysis: a journey to migratory carboboration of alkenes
Y Li, G Yin - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Chain-walking offers extensive opportunities for innovating synthetic methods
that involve constructing chemical bonds at unconventional sites. This approach provides …
that involve constructing chemical bonds at unconventional sites. This approach provides …
Diboron (4)‐catalyzed remote [3+ 2] cycloaddition of cyclopropanes via dearomative/rearomative radical transmission through pyridine
M Xu, Z Wang, Z Sun, Y Ouyang, Z Ding… - Angewandte …, 2022 - Wiley Online Library
Ring structures such as pyridine, cyclopentane or their combinations are important motifs in
bioactive molecules. In contrast to previous cycloaddition reactions that necessitated a …
bioactive molecules. In contrast to previous cycloaddition reactions that necessitated a …
Copper-catalyzed borylative difunctionalization of π-systems
Organoboronates represent a cornerstone functional group in modern synthesis owing to
their unique reactivity and divergent synthetic capability. Copper catalysis has become one …
their unique reactivity and divergent synthetic capability. Copper catalysis has become one …
Recent advances in the synthesis of difluorinated architectures from trifluoromethyl groups
F Zhao, W Zhou, Z Zuo - Advanced Synthesis & Catalysis, 2022 - Wiley Online Library
Fluorine‐containing moieties are widely used in the pharmaceutical, agrochemical, and
material fields. Thus, these structures are of immense interest in the fields of organic …
material fields. Thus, these structures are of immense interest in the fields of organic …