Structure and reactivity/selectivity control by oriented-external electric fields
This is a tutorial on use of external-electric-fields (EEFs) as effectors of chemical change.
The tutorial instructs readers how to conceptualize and design electric-field effects on bonds …
The tutorial instructs readers how to conceptualize and design electric-field effects on bonds …
Frustrated Lewis pair chemistry: development and perspectives
DW Stephan, G Erker - Angewandte Chemie International …, 2015 - Wiley Online Library
Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …
solution that are deterred from strong adduct formation by steric and/or electronic factors …
Can electric fields drive chemistry for an aqueous microdroplet?
Reaction rates of common organic reactions have been reported to increase by one to six
orders of magnitude in aqueous microdroplets compared to bulk solution, but the reasons for …
orders of magnitude in aqueous microdroplets compared to bulk solution, but the reasons for …
Insights into the mechanism of coreactant electrochemiluminescence facilitating enhanced bioanalytical performance
Electrochemiluminescence (ECL) is a powerful transduction technique with a leading role in
the biosensing field due to its high sensitivity and low background signal. Although the …
the biosensing field due to its high sensitivity and low background signal. Although the …
Frustrated lewis pairs
DW Stephan - Journal of the American Chemical Society, 2015 - ACS Publications
The articulation of the notion of “frustrated Lewis pairs”(FLPs), which emerged from the
discovery that H2 can be reversibly activated by combinations of sterically encumbered …
discovery that H2 can be reversibly activated by combinations of sterically encumbered …
Oriented electric fields as future smart reagents in chemistry
Oriented external electric fields (OEEFs) as' smart reagents' are no longer a theoretical
dream. Here, we discuss the wide-ranging potential of using OEEFs to catalyse and control …
dream. Here, we discuss the wide-ranging potential of using OEEFs to catalyse and control …
Metallomimetic chemistry of boron
The study of main-group molecules that behave and react similarly to transition-metal (TM)
complexes has attracted significant interest in recent decades. Most notably, the attractive …
complexes has attracted significant interest in recent decades. Most notably, the attractive …
A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes
M Oestreich, J Hermeke, J Mohr - Chemical Society Reviews, 2015 - pubs.rsc.org
The bond activation chemistry of B (C6F5) 3 and related electron-deficient boranes is
currently experiencing a renaissance due to the fascinating development of frustrated Lewis …
currently experiencing a renaissance due to the fascinating development of frustrated Lewis …
Chemie frustrierter Lewis‐Paare: Entwicklung und Perspektiven
DW Stephan, G Erker - Angewandte Chemie, 2015 - Wiley Online Library
Abstract Der Begriff “frustrierte Lewis‐Paare”(FLPs) bezeichnet Kombinationen von Lewis‐
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …
External electric field effects on chemical structure and reactivity
In recent years, external electric fields (EEFs) have captured some spotlight as novel
effectors of chemical change. EEFs directly impact the structure of molecular systems. For …
effectors of chemical change. EEFs directly impact the structure of molecular systems. For …