Structure and reactivity/selectivity control by oriented-external electric fields

S Shaik, R Ramanan, D Danovich… - Chemical Society …, 2018 - pubs.rsc.org
This is a tutorial on use of external-electric-fields (EEFs) as effectors of chemical change.
The tutorial instructs readers how to conceptualize and design electric-field effects on bonds …

Frustrated Lewis pair chemistry: development and perspectives

DW Stephan, G Erker - Angewandte Chemie International …, 2015 - Wiley Online Library
Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …

Can electric fields drive chemistry for an aqueous microdroplet?

H Hao, I Leven, T Head-Gordon - Nature communications, 2022 - nature.com
Reaction rates of common organic reactions have been reported to increase by one to six
orders of magnitude in aqueous microdroplets compared to bulk solution, but the reasons for …

Insights into the mechanism of coreactant electrochemiluminescence facilitating enhanced bioanalytical performance

A Zanut, A Fiorani, S Canola, T Saito, N Ziebart… - Nature …, 2020 - nature.com
Electrochemiluminescence (ECL) is a powerful transduction technique with a leading role in
the biosensing field due to its high sensitivity and low background signal. Although the …

Frustrated lewis pairs

DW Stephan - Journal of the American Chemical Society, 2015 - ACS Publications
The articulation of the notion of “frustrated Lewis pairs”(FLPs), which emerged from the
discovery that H2 can be reversibly activated by combinations of sterically encumbered …

Oriented electric fields as future smart reagents in chemistry

S Shaik, D Mandal, R Ramanan - Nature chemistry, 2016 - nature.com
Oriented external electric fields (OEEFs) as' smart reagents' are no longer a theoretical
dream. Here, we discuss the wide-ranging potential of using OEEFs to catalyse and control …

Metallomimetic chemistry of boron

MA Légaré, C Pranckevicius, H Braunschweig - Chemical reviews, 2019 - ACS Publications
The study of main-group molecules that behave and react similarly to transition-metal (TM)
complexes has attracted significant interest in recent decades. Most notably, the attractive …

A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes

M Oestreich, J Hermeke, J Mohr - Chemical Society Reviews, 2015 - pubs.rsc.org
The bond activation chemistry of B (C6F5) 3 and related electron-deficient boranes is
currently experiencing a renaissance due to the fascinating development of frustrated Lewis …

Chemie frustrierter Lewis‐Paare: Entwicklung und Perspektiven

DW Stephan, G Erker - Angewandte Chemie, 2015 - Wiley Online Library
Abstract Der Begriff “frustrierte Lewis‐Paare”(FLPs) bezeichnet Kombinationen von Lewis‐
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …

External electric field effects on chemical structure and reactivity

T Stuyver, D Danovich, J Joy… - Wiley Interdisciplinary …, 2020 - Wiley Online Library
In recent years, external electric fields (EEFs) have captured some spotlight as novel
effectors of chemical change. EEFs directly impact the structure of molecular systems. For …