Spin crossover iron complexes with spin transition near room temperature based on nitrogen ligands containing aromatic rings: from molecular design to functional …

Y Zhang, R Torres-Cavanillas, X Yan, Y Zeng… - Chemical Society …, 2024 - pubs.rsc.org
During last decades, significant advances have been made in iron-based spin crossover
(SCO) complexes, with a particular emphasis on achieving reversible and reproducible …

Unusual Electronic Structures of an Electron Transfer Series of [Cr(μη1 : η1‐N2)Cr]0/1+/2+

GX Wang, C Shan, W Chen, B Wu, P Zhang… - Angewandte …, 2024 - Wiley Online Library
In dinitrogen (N2) fixation chemistry, bimetallic end‐on bridging N2 complexes M (μ‐η1: η1‐
N2) M can split N2 into terminal nitrides and hence attract great attention. To date, only 4d …

An overview of the synthesis, structures and magnetic properties of dinuclear iron complexes with salen type Schiff base ligands

P Middya, A Konar, S Chattopadhyay - Journal of Molecular Structure, 2024 - Elsevier
An overview of the synthesis, structures and magnetic properties of dinuclear iron complexes
with salen type Schiff base ligands - ScienceDirect Skip to main contentSkip to article Elsevier …

Tuning valence tautomerism in a family of dinuclear cobalt complexes incorporating a conjugated bridging bis (dioxolene) ligand with weak communication

TE Fischer, JT Janetzki, FZM Zahir, RW Gable… - Dalton …, 2024 - pubs.rsc.org
Valence tautomerism (VT) involves the stimulated reversible intramolecular electron transfer
between a redox-active metal and ligand. Dinuclear cobalt complexes bridged by bis …

Binucleating Jäger-type {(N 2 O 2) 2} 4− ligands: magnetic and electronic interactions of Fe (ii), Ni (ii) and Cu (ii) across an in-plane TTF-bridge

C Schreck, S Schönfeld, P Liebing, G Hörner… - Dalton …, 2024 - pubs.rsc.org
The simultaneous presence of different electrophores provides an interesting playground for
responsive materials. Herein, we present the incorporation of a twice-reversibly oxidizable …

Tuning Valence Tautomerism in Dinuclear Cobalt Complexes by Modulating Communication in the Bridging Ligand

JT Janetzki, GK Gransbury, RW Gable… - European Journal of …, 2024 - Wiley Online Library
The capability of bis (dioxolene) ligands to access multiple redox states makes them ideal
candidates to tune the electronic properties of metal complexes, for example to achieve …