Fe (II) redox chemistry in the environment

J Huang, A Jones, TD Waite, Y Chen, X Huang… - Chemical …, 2021 - ACS Publications
Iron (Fe) is the fourth most abundant element in the earth's crust and plays important roles in
both biological and chemical processes. The redox reactivity of various Fe (II) forms has …

Iron redox cycling in layered clay minerals and its impact on contaminant dynamics: A review

Q Fan, L Wang, Y Fu, Q Li, Y Liu, Z Wang… - Science of the Total …, 2023 - Elsevier
A majority of clay minerals contain Fe, and the redox cycling of Fe (III)/Fe (II) in clay minerals
has been extensively studied as it may fuel the biogeochemical cycles of nutrients and …

Photo-assisted reductive cleavage and catalytic hydrolysis-mediated persulfate activation by mixed redox-couple-involved CuFeS2 for efficient trichloroethylene …

J Huang, Y Zhou, S Deng, Y Shangguan, R Wang… - Water Research, 2022 - Elsevier
Abstract Persulfate (PS, S 2 O 8 2−) activation through transition metal sulfides (TMS) has
gained increasing attention since it can decompose a wide variety of refractory halogenated …

Highly efficient removal of hexavalent chromium from electroplating wastewater by ferrous/ferric hydroxide complex: From lab-scale to pilot-scale study

X Lin, L Xu, Z Zhao, S Liu, J Zhang, D Wu - Chemical Engineering Journal, 2023 - Elsevier
Low electron-transfer efficiency and cumbersome processes are widely known to negatively
affect the application of Fe-based materials for treating electroplating wastewater. In this …

Abiotic reduction of organic and inorganic compounds by Fe (II)-associated reductants: comprehensive data sets and machine learning modeling

Y Gao, S Zhong, K Zhang, H Zhang - Environmental Science & …, 2023 - ACS Publications
Iron-associated reductants play a crucial role in providing electrons for various reductive
transformations. However, developing reliable predictive tools for estimating abiotic …

[HTML][HTML] Biotic and abiotic reductive dechlorination of chloroethenes in aquitards

D Puigserver, J Herrero, X Nogueras, A Cortés… - Science of The Total …, 2022 - Elsevier
Chlorinated solvents occur as dense nonaqueous phase liquid (DNAPL) or as solutes when
dissolved in water. They are present in many pollution sites in urban and industrial areas …

Insights into the degradation process of phenol during in-situ thermal desorption: The overlooked oxidation of hydroxyl radicals from oxygenation of reduced Fe …

W Zhang, X Li, J Shen, Z Sun, X Zhou, F Li, F Ma… - Journal of Hazardous …, 2023 - Elsevier
In-situ thermal desorption (ISTD) has attracted increasing attention owing to the efficient
removal of organic contaminants from contaminated sites. However, it is poorly understood …

Impact of environmental factors on the removal of chloramphenicol by zero-valent iron and pyrite mixture

Y Lv, L Han, J Shen, J Li, H Dong, J Hu, Y He… - Separation and …, 2024 - Elsevier
Chloramphenicol (CAP) is an effective bacteriostatic pharmaceutical that has been widely
applied in clinical prescriptions, animal husbandry and aquaculture, but the residues …

[HTML][HTML] Nitrogen amended graphene catalyses fast reduction of vinyl chloride by nano zerovalent iron

Q Ouyang, HCB Hansen, LG Thygesen, DJ Tobler - Water Research, 2023 - Elsevier
Vinyl chloride (VC) is a dominant carcinogenic residual in many aged chlorinated solvent
plumes, and it remains a huge challenge to clean it up. Zerovalent iron (ZVI) is an effective …

Efficient full dechlorination of chlorinated ethenes on single enzyme-like Co− N4 sites in nitrogen-doped carbons

H Qin, T Zha, K Qian, Y Sun, X Guan, C Chen - Applied Catalysis B …, 2023 - Elsevier
Chlorinated ethenes are ubiquitous contaminants in groundwater. Here, by embedment of
enzyme-like Co− N 4 sites in the nitrogen-doped carbon support, we prepared a Co− NC …