Reactive p-block cations stabilized by weakly coordinating anions
TA Engesser, MR Lichtenthaler, M Schleep… - Chemical Society …, 2016 - pubs.rsc.org
The chemistry of the p-block elements is a huge playground for fundamental and applied
work. With their bonding from electron deficient to hypercoordinate and formally hypervalent …
work. With their bonding from electron deficient to hypercoordinate and formally hypervalent …
Heterocyclic crown ethers with potential biological and pharmacological properties: From synthesis to applications
Cyclic organic compounds with several ether linkages in their structure are of much concern
in our daily life applications. Crown ethers (CEs) are generally heterocyclic and extremely …
in our daily life applications. Crown ethers (CEs) are generally heterocyclic and extremely …
Decorating Channel Walls in Metal–Organic Frameworks with Crown Ethers for Efficient and Selective Separation of Radioactive Strontium (II)
L Feng, X Chen, M Cao, S Zhao… - Angewandte Chemie …, 2023 - Wiley Online Library
Nuclear accidents and the improper disposal of nuclear wastes have led to serious
environmental radioactive pollutions. The rational design of adsorbents for the highly …
environmental radioactive pollutions. The rational design of adsorbents for the highly …
Amphoteric reactivity of metal–oxygen complexes in oxidation reactions
M Sankaralingam, YM Lee, W Nam… - Coordination Chemistry …, 2018 - Elsevier
Mononuclear metal–oxygen species, such as metal-superoxo,-peroxo,-hydroperoxo and-
oxo complexes, are key intermediates involved in dioxygen activation and oxidation …
oxo complexes, are key intermediates involved in dioxygen activation and oxidation …
Lewis Base Mediated Autoionization of GeCl2 and SnCl2
Cationic and anionic species of heavier low-valent group 14 elements are intriguing targets
in main group chemistry due to their synthetic potential and industrial applications. In the …
in main group chemistry due to their synthetic potential and industrial applications. In the …
[PDF][PDF] Weak Arene Stabilization of Bulky Amido‐Germanium (II) and Tin (II) Monocations
The last two decades have seen much progress in extending the chemistry of classical
carbenium ions, R3C+, to their heavier Group14 counterparts, R3E+(E= Si, Ge, Sn, or Pb).[1] …
carbenium ions, R3C+, to their heavier Group14 counterparts, R3E+(E= Si, Ge, Sn, or Pb).[1] …
Cations and dications of heavier group 14 elements in low oxidation states
Cations and dications of heavier group 14 elements in their low oxidation state have
received widespread attention in recent years. The journey started with the isolation of a …
received widespread attention in recent years. The journey started with the isolation of a …
Stabilization of a two-coordinate [GeCl]+ cation by simultaneous σ and π donation from a monodentate carbodiphosphorane
S Khan, G Gopakumar, W Thiel… - … International Edition: a …, 2013 - pure.mpg.de
Give me four: The synthesis, structure, and reactivity of [GeCl]+ and [SnCl]+ cations bearing
a carbodiphosphorane as ancillary ligand are presented. In the Ge compound, simultaneous …
a carbodiphosphorane as ancillary ligand are presented. In the Ge compound, simultaneous …
Isolation and Structure of Germylene‐Germyliumylidenes Stabilized by N‐Heterocyclic Imines
T Ochiai, T Szilvási, D Franz, E Irran… - Angewandte …, 2016 - Wiley Online Library
The ditopic germanium complex FGe (NIPr) 2Ge [BF4](3 [BF4]; IPr= 1, 3‐bis (2, 6‐
diisopropylphenyl) imidazolin‐2‐ylidene) is prepared by the reaction of the amino (imino) …
diisopropylphenyl) imidazolin‐2‐ylidene) is prepared by the reaction of the amino (imino) …
Synthesis and Unexpected Reactivity of Germyliumylidene Hydride [:GeH]+ Stabilized by a Bis(N-heterocyclic carbene)borate Ligand
Employing the potassium salt of the monoanionic bis (NHC) borate 1 (NHC= NH eterocyclic
C arbene) enables the synthesis and isolation of the bis (NHC) borate-stabilized …
C arbene) enables the synthesis and isolation of the bis (NHC) borate-stabilized …