Imaging the dynamics of catalysed surface reactions by in situ scanning electron microscopy
Analytical methods that provide direct real-space information about the dynamics of
catalysed reactions often require simplified model systems and operate under high-vacuum …
catalysed reactions often require simplified model systems and operate under high-vacuum …
From atomistic to collective dynamics: Bridging gaps in gas-phase electron microscopy for catalysis
TW Hansen, M Willinger - MRS Bulletin, 2023 - Springer
Catalysis is a highly complex phenomenon involving fundamental processes on multiple
length scales. The full-scale complexity of catalysis is only poorly understood, and how …
length scales. The full-scale complexity of catalysis is only poorly understood, and how …
Influence of dipole–dipole interactions on coverage-dependent adsorption: CO and NO on Pt (111)
Density functional theory (DFT) calculations of energetic, geometric, vibrational, and
electrostatic properties of different arrangements of CO and NO at quarter and half …
electrostatic properties of different arrangements of CO and NO at quarter and half …
Reducing reaction temperature, steam requirements, and coke formation during methane steam reforming using electric fields: a microkinetic modeling and …
In this study, we approach several common problems with the Ni-catalyzed methane steam
reformation reaction (MSR) using a two-pronged approach combining density functional …
reformation reaction (MSR) using a two-pronged approach combining density functional …
Dynamic processes on gold-based catalysts followed by environmental microscopies
Since the early discovery of the catalytic activity of gold at low temperature, there has been a
growing interest in Au and Au-based catalysis for a new class of applications. The …
growing interest in Au and Au-based catalysis for a new class of applications. The …
Emergence of chemical oscillations from nanosized target patterns
This work investigates experimentally the mechanism by which chemical oscillations
emerge in a nanometric system. We monitor the spatiotemporal dynamics of an oscillating …
emerge in a nanometric system. We monitor the spatiotemporal dynamics of an oscillating …
Complex Oscillation Patterns During the Catalytic Hydrogenation of NO2 over Platinum Nanosized Crystals
C Barroo, Y De Decker… - The Journal of …, 2014 - ACS Publications
We studied the catalytic reduction of NO2 with hydrogen on platinum model catalysts by
means of field emission techniques. Atomic resolution field ion microscopy (FIM) was used …
means of field emission techniques. Atomic resolution field ion microscopy (FIM) was used …
Oxygen adsorption, subsurface oxygen layer formation and reaction with hydrogen on surfaces of a Pt–Rh alloy nanocrystal
S Owczarek, SV Lambeets, R Bryl, C Barroo… - Topics in …, 2020 - Springer
The oxygen adsorption and its catalytic reaction with hydrogen on Pt–Rh single crystals
were studied at the nanoscale by Field Emission Microscopy (FEM) and Field Ion …
were studied at the nanoscale by Field Emission Microscopy (FEM) and Field Ion …
Fluctuating dynamics of nanoscale chemical oscillations: theory and experiments
C Barroo, Y De Decker… - The Journal of …, 2015 - ACS Publications
Chemical oscillations are observed in a variety of reactive systems, including biological
cells, for the functionality of which they play a central role. However, at such scales …
cells, for the functionality of which they play a central role. However, at such scales …
Nonlinear behavior during NO2 hydrogenation on a nanosized Pt-Rh catalyst sample
Automotive pollution control crucially relies on the reactivity of metal alloy catalysts.
Understanding how the chemistry of an alloy compares with that of pure metals forms a …
Understanding how the chemistry of an alloy compares with that of pure metals forms a …