Microstructural and dynamical heterogeneities in ionic liquids
Ionic liquids (ILs) are a special category of molten salts solely composed of ions with varied
molecular symmetry and charge delocalization. The versatility in combining varied cation …
molecular symmetry and charge delocalization. The versatility in combining varied cation …
NMR relaxometry accessing the relaxation spectrum in molecular glass formers
M Becher, A Lichtinger, R Minikejew, M Vogel… - International Journal of …, 2022 - mdpi.com
It is a longstanding question whether universality or specificity characterize the molecular
dynamics underlying the glass transition of liquids. In particular, there is an ongoing debate …
dynamics underlying the glass transition of liquids. In particular, there is an ongoing debate …
p-Toluenesulfonic Acid-Based Deep-Eutectic Solvents for Solubilizing Metal Oxides
N Rodriguez Rodriguez, L Machiels… - ACS Sustainable …, 2019 - ACS Publications
Combinations of p-toluenesulfonic acid monohydrate with different hydrogen-bond
acceptors (ie, choline chloride, tetraethylammonium chloride, tetrabutylammonium chloride …
acceptors (ie, choline chloride, tetraethylammonium chloride, tetrabutylammonium chloride …
[HTML][HTML] A novel phosphonium ionic liquid electrolyte enabling high-voltage and high-energy positive electrode materials in lithium-metal batteries
The synthesis of a new ionic liquid (IL), consisting of the symmetric tetra-butyl-phosphonium
(P 4444+) cation and the (nonafluorobutanesulfonyl)(trifluoromethanesulfonyl) imide (IM 14 …
(P 4444+) cation and the (nonafluorobutanesulfonyl)(trifluoromethanesulfonyl) imide (IM 14 …
Structural Features of Styrene-Functionalized Cyclodextrin Polymers That Promote the Adsorption of Perfluoroalkyl Acids in Water
Cross-linked β-cyclodextrin (β-CD) polymers are promising adsorbents for the removal of
per-and polyfluoroalkyl substances (PFAS) from contaminated water sources, including …
per-and polyfluoroalkyl substances (PFAS) from contaminated water sources, including …
Effect of bulky anions on the liquid-liquid phase transition in phosphonium ionic liquids: Ambient and high-pressure dielectric studies
Although the first-order liquid–liquid phase transition (LLT) has been reported to exist in
various systems (ie, phosphorus, silicon, water, triphenyl phosphite, etc.), it is still one of the …
various systems (ie, phosphorus, silicon, water, triphenyl phosphite, etc.), it is still one of the …
Novel phosphonium-based ionic liquid electrolytes for battery applications
A Hofmann, D Rauber, TM Wang, R Hempelmann… - Molecules, 2022 - mdpi.com
In this study, we address the fundamental question of the physicochemical and
electrochemical properties of phosphonium-based ionic liquids containing the counter-ions …
electrochemical properties of phosphonium-based ionic liquids containing the counter-ions …
Mesoscale organization and dynamics in binary ionic liquid mixtures
The impact of mesoscale organization on dynamics and ion transport in binary ionic liquid
mixtures is investigated by broad-band dielectric spectroscopy, dynamic-mechanical …
mixtures is investigated by broad-band dielectric spectroscopy, dynamic-mechanical …
Ion transport in glassy polymerized ionic liquids: Unraveling the impact of the molecular structure
The impact of molecular structure on ion dynamics and morphology in ammonium-and
imidazolium-based glassy polymerized ionic liquids (polyILs) is investigated using …
imidazolium-based glassy polymerized ionic liquids (polyILs) is investigated using …
On the relation between reorientation and diffusion in glass-forming ionic liquids with micro-heterogeneous structures
M Becher, E Steinrücken, M Vogel - The Journal of chemical physics, 2019 - pubs.aip.org
We investigate complex structure-dynamics relations in glass-forming ionic liquids
comprising 1-alkyl-3-methylimidazolium cations and bis (trifluoromethylsulfonyl) imide …
comprising 1-alkyl-3-methylimidazolium cations and bis (trifluoromethylsulfonyl) imide …