Transition‐metal‐catalyzed carboxylation reactions with carbon dioxide

A Tortajada, F Juliá‐Hernández… - Angewandte Chemie …, 2018 - Wiley Online Library
Driven by the inherent synthetic potential of CO2 as an abundant, inexpensive and
renewable C1 chemical feedstock, the recent years have witnessed renewed interest in …

Transition metal-catalyzed carboxylation of unsaturated substrates with CO2

SS Yan, Q Fu, LL Liao, GQ Sun, JH Ye, L Gong… - Coordination Chemistry …, 2018 - Elsevier
The utilization of CO 2 as a C1 building block for the synthesis of valuable chemicals is of
great importance. The transition metal-catalyzed carboxylation of unsaturated substrates …

Visible-Light-Driven Catalytic Reductive Carboxylation with CO2

Z Zhang, JH Ye, T Ju, LL Liao, H Huang, YY Gui… - ACS …, 2020 - ACS Publications
Carbon dioxide (CO2) is an important C1 source for the generation of important carboxylic
acids and derivatives. Stoichiometric and catalytic carboxylation of nucleophiles, including …

Construction of a visible light-driven hydrocarboxylation cycle of alkenes by the combined use of Rh (I) and photoredox catalysts

K Murata, N Numasawa, K Shimomaki… - Chemical …, 2017 - pubs.rsc.org
A visible light driven catalytic cycle for hydrocarboxylation of alkenes with CO2 was
established using a combination of a Rh (I) complex as a carboxylation catalyst and [Ru …

Development of an improved system for the carboxylation of aryl halides through mechanistic studies

DJ Charboneau, GW Brudvig, N Hazari, HMC Lant… - ACS …, 2019 - ACS Publications
The nickel-catalyzed carboxylation of organic halides or pseudohalides using carbon
dioxide is an emerging method to prepare synthetically valuable carboxylic acids. Here, we …

Carbon dioxide based methodologies for the synthesis of fine chemicals

DA Sable, KS Vadagaonkar, AR Kapdi… - Organic & Biomolecular …, 2021 - pubs.rsc.org
Rapid environmental changes triggered by the increase in the concentration of heat-
absorbing gases such as CO2 in the atmosphere have become a major cause of concern …

Ni- and Fe-catalyzed Carboxylation of Unsaturated Hydrocarbons with CO2

F Juliá-Hernández, M Gaydou, E Serrano… - Ni-and Fe-Based Cross …, 2017 - Springer
The sustainable utilization of available feedstock materials for preparing valuable
compounds holds great promise to revolutionize approaches in organic synthesis. In this …

Recent progress in the cyclization reactions using carbon dioxide

W Zhang, N Zhang, C Guo, X Lü - Chinese Journal of Organic …, 2017 - sioc-journal.cn
Carbon dioxide is a cheap, abundant and renewable C 1 feedstock. Methodology study on
the transformation of carbon dioxide into highly value-added chemicals has become one of …

Übergangsmetallkatalysierte Carboxylierungen mit Kohlendioxid

A Tortajada, F Juliá‐Hernández… - Angewandte …, 2018 - Wiley Online Library
In den letzten Jahren hat das Interesse an katalytischen Reaktionen zum Einbau von CO2
als allgegenwärtigem und preisgünstigem C1‐Rohstoff in organischen Stoffen aufs Neue …

Metal–Ligand Cooperation as Key in Formation of Dearomatized NiII–H Pincer Complexes and in Their Reactivity toward CO and CO2

D Oren, Y Diskin-Posner, L Avram, M Feller… - …, 2018 - ACS Publications
The unique synthesis and reactivity of [(RPNP*) NiH] complexes (1a, b), based on metal–
ligand cooperation (MLC), are presented (RPNP*= deprotonated PNP ligand, R= iPr, tBu) …