Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …

This perspective is to illustrate the synthesis and applications of bimetallic complexes by
merging a metallocene and a (cyclopentadienyl/aryl) pincer metal complex. Four possible …

We use a ligand design strategy to isolate a cyclometalated nickel (IV) complex that is
directly analogous to a key intermediate proposed in aminoquinoline-directed C–H …

We show that the carboxylate radical acts as an L-ligand with certain high-spin transition
metal centers. Such coordination preserves the O-radical character needed for C–H …

Herein, we report a Pd (II)-catalyzed β-C (sp3)–H nitrooxylation of ketones and native
amides. The fine-tuned removable aminooxyamide auxiliary enabled β-C (sp3)–H …

Herein, we report an electrocatalytic hydrofluorination of aryl-substituted alkenes with a
nucleophilic fluorine source. The merger of palladium catalysis with electrooxidation …

Metathesis reactions represent powerful synthetic tools that have been used in a number of
fields from the synthesis of natural product to functional material preparation. However, the C …

In this article, we investigated the I2-promoted cyclic dialkyl ether formation from 6-
membered oxanickelacycles originally reported by Hillhouse. A detailed mechanistic …

Directed C–H arylations have proven to be some of the most advantageous strategies for the
synthesis of biaryls. However, their sensitivity toward steric hindrance is a key limitation …

Isodesmic reactions represent mild alternatives to other chemical transformations that
require harsh oxidizing agents or highly reactive intermediates. However, enantioselective …