Nanographenes and graphene nanoribbons as multitalents of present and future materials science

Y Gu, Z Qiu, K Müllen - Journal of the American Chemical …, 2022 - ACS Publications
As cut-outs from a graphene sheet, nanographenes (NGs) and graphene nanoribbons
(GNRs) are ideal cases with which to connect the world of molecules with that of bulk carbon …

Chiroptical properties of symmetric double, triple, and multiple helicenes

T Mori - Chemical Reviews, 2021 - ACS Publications
Helicenes have attracted considerable attention due to their inherent helical chirality and
extended π-conjugation. Recently, rapid progress has been witnessed in the preparation of …

Heteroatom-doped nanographenes with structural precision

XY Wang, X Yao, A Narita… - Accounts of Chemical …, 2019 - ACS Publications
Conspectus Nanographenes, which are defined as nanoscale (1–100 nm) graphene
cutouts, include quasi-one-dimensional graphene nanoribbons (GNRs) and quasi-zero …

Polycyclic aromatic hydrocarbon-based organic semiconductors: ring-closing synthesis and optoelectronic properties

Q Li, Y Zhang, Z Xie, Y Zhen, W Hu… - Journal of Materials …, 2022 - pubs.rsc.org
Polycyclic aromatic hydrocarbons (PAHs) as a typical class of organic semiconductors
demonstrate unique optical, electrical, magnetic and other interesting properties due to their …

Recent progress in chemistry of multiple helicenes

C Li, Y Yang, Q Miao - Chemistry–An Asian Journal, 2018 - Wiley Online Library
The last decade has witnessed multiple helicenes arising as an interesting class of
nonplanar polycyclic aromatics of inherent multihelicity. These molecules present esthetic …

Dinor [7] helicene and Beyond: Divergent Synthesis of Chiral Diradicaloids with Variable Open‐Shell Character

A Borissov, PJ Chmielewski… - Angewandte Chemie …, 2023 - Wiley Online Library
Diradicaloid helicenes constructed formally by non‐benzenoid double π‐extension of
phenanthrene were synthesized by a common strategy involving double electrophilic …

Quadruply B← N-fused dibenzo-azaacene with high electron affinity and high electron mobility

Y Min, C Dou, D Liu, H Dong, J Liu - Journal of the American …, 2019 - ACS Publications
For many years, organoboron compounds have been expected to show excellent electron-
injecting and-transporting properties. However, lowest unoccupied molecular orbital (LUMO) …

Multiple helicenes featuring synthetic approaches and molecular structures

A Tsurusaki, K Kamikawa - Chemistry Letters, 2021 - academic.oup.com
Helicenes are attractive non-planar polycyclic aromatic hydrocarbons with unique optical
and electronic properties. In recent years, the chemistry of “multiple helicenes” with plural …

Symmetric multiple carbohelicenes

K Kato, Y Segawa, K Itami - Synlett, 2019 - thieme-connect.com
This account focuses on the synthesis and structures of symmetric multiple carbohelicenes;
ie, fully fused polycyclic aromatic hydrocarbons containing two or more symmetric helicene …

Open-shell and antiaromatic character induced by the highly symmetric geometry of the planar heptalene structure: synthesis and characterization of a nonalternant …

A Konishi, K Horii, D Shiomi, K Sato… - Journal of the …, 2019 - ACS Publications
A nonbenzenoid hydrocarbon, difluoreno [1, 9, 8-alkj: 1′, 9′, 8′-gfed] heptalene 1, is
synthesized. Experimental and theoretical investigations demonstrate that the planar and …