Nanographenes and graphene nanoribbons as multitalents of present and future materials science
As cut-outs from a graphene sheet, nanographenes (NGs) and graphene nanoribbons
(GNRs) are ideal cases with which to connect the world of molecules with that of bulk carbon …
(GNRs) are ideal cases with which to connect the world of molecules with that of bulk carbon …
Chiroptical properties of symmetric double, triple, and multiple helicenes
T Mori - Chemical Reviews, 2021 - ACS Publications
Helicenes have attracted considerable attention due to their inherent helical chirality and
extended π-conjugation. Recently, rapid progress has been witnessed in the preparation of …
extended π-conjugation. Recently, rapid progress has been witnessed in the preparation of …
Heteroatom-doped nanographenes with structural precision
Conspectus Nanographenes, which are defined as nanoscale (1–100 nm) graphene
cutouts, include quasi-one-dimensional graphene nanoribbons (GNRs) and quasi-zero …
cutouts, include quasi-one-dimensional graphene nanoribbons (GNRs) and quasi-zero …
Polycyclic aromatic hydrocarbon-based organic semiconductors: ring-closing synthesis and optoelectronic properties
Q Li, Y Zhang, Z Xie, Y Zhen, W Hu… - Journal of Materials …, 2022 - pubs.rsc.org
Polycyclic aromatic hydrocarbons (PAHs) as a typical class of organic semiconductors
demonstrate unique optical, electrical, magnetic and other interesting properties due to their …
demonstrate unique optical, electrical, magnetic and other interesting properties due to their …
Recent progress in chemistry of multiple helicenes
C Li, Y Yang, Q Miao - Chemistry–An Asian Journal, 2018 - Wiley Online Library
The last decade has witnessed multiple helicenes arising as an interesting class of
nonplanar polycyclic aromatics of inherent multihelicity. These molecules present esthetic …
nonplanar polycyclic aromatics of inherent multihelicity. These molecules present esthetic …
Dinor [7] helicene and Beyond: Divergent Synthesis of Chiral Diradicaloids with Variable Open‐Shell Character
A Borissov, PJ Chmielewski… - Angewandte Chemie …, 2023 - Wiley Online Library
Diradicaloid helicenes constructed formally by non‐benzenoid double π‐extension of
phenanthrene were synthesized by a common strategy involving double electrophilic …
phenanthrene were synthesized by a common strategy involving double electrophilic …
Quadruply B← N-fused dibenzo-azaacene with high electron affinity and high electron mobility
Y Min, C Dou, D Liu, H Dong, J Liu - Journal of the American …, 2019 - ACS Publications
For many years, organoboron compounds have been expected to show excellent electron-
injecting and-transporting properties. However, lowest unoccupied molecular orbital (LUMO) …
injecting and-transporting properties. However, lowest unoccupied molecular orbital (LUMO) …
Multiple helicenes featuring synthetic approaches and molecular structures
A Tsurusaki, K Kamikawa - Chemistry Letters, 2021 - academic.oup.com
Helicenes are attractive non-planar polycyclic aromatic hydrocarbons with unique optical
and electronic properties. In recent years, the chemistry of “multiple helicenes” with plural …
and electronic properties. In recent years, the chemistry of “multiple helicenes” with plural …
Symmetric multiple carbohelicenes
This account focuses on the synthesis and structures of symmetric multiple carbohelicenes;
ie, fully fused polycyclic aromatic hydrocarbons containing two or more symmetric helicene …
ie, fully fused polycyclic aromatic hydrocarbons containing two or more symmetric helicene …
Open-shell and antiaromatic character induced by the highly symmetric geometry of the planar heptalene structure: synthesis and characterization of a nonalternant …
A nonbenzenoid hydrocarbon, difluoreno [1, 9, 8-alkj: 1′, 9′, 8′-gfed] heptalene 1, is
synthesized. Experimental and theoretical investigations demonstrate that the planar and …
synthesized. Experimental and theoretical investigations demonstrate that the planar and …