Nanoporous gold: From structure evolution to functional properties in catalysis and electrochemistry

G Wittstock, M Bäumer, W Dononelli… - Chemical …, 2023 - ACS Publications
Nanoporous gold (NPG) is characterized by a bicontinuous network of nanometer-sized
metallic struts and interconnected pores formed spontaneously by oxidative dissolution of …

[HTML][HTML] Understanding the complementarities of surface-enhanced infrared and Raman spectroscopies in CO adsorption and electrochemical reduction

X Chang, S Vijay, Y Zhao, NJ Oliveira, K Chan… - Nature …, 2022 - nature.com
In situ/operando surface enhanced infrared and Raman spectroscopies are widely
employed in electrocatalysis research to extract mechanistic information and establish …

[HTML][HTML] Surface chemistry in nanoscale materials

J Biener, A Wittstock, TF Baumann, J Weissmüller… - Materials, 2009 - mdpi.com
Although surfaces or, more precisely, the surface atomic and electronic structure, determine
the way materials interact with their environment, the influence of surface chemistry on the …

Inhibited proton transfer enhances Au-catalyzed CO2-to-fuels selectivity

A Wuttig, M Yaguchi, K Motobayashi… - Proceedings of the …, 2016 - National Acad Sciences
CO2 reduction in aqueous electrolytes suffers efficiency losses because of the simultaneous
reduction of water to H2. We combine in situ surface-enhanced IR absorption spectroscopy …

Nickel-Laden Dendritic Plasmonic Colloidosomes of Black Gold: Forced Plasmon Mediated Photocatalytic CO2 Hydrogenation

R Verma, R Belgamwar, P Chatterjee… - ACS …, 2023 - ACS Publications
In this work, we have designed and synthesized nickel-laden dendritic plasmonic
colloidosomes of Au (black gold-Ni). The photocatalytic CO2 hydrogenation activities of …

Surface-chemistry-driven actuation in nanoporous gold

J Biener, A Wittstock, LA Zepeda-Ruiz, MM Biener… - Nature materials, 2009 - nature.com
Although actuation in biological systems is exclusively powered by chemical energy, this
concept has not been realized in man-made actuator technologies, as these rely on …

Nanoporous gold: a new material for catalytic and sensor applications

A Wittstock, J Biener, M Bäumer - Physical Chemistry Chemical …, 2010 - pubs.rsc.org
Nanostructured materials are governed by their surface chemical properties. This is
strikingly reflected by np-Au. This material can be generated by corrosion of bulk Ag–Au …

Nanoporous gold: understanding the origin of the reactivity of a 21st century catalyst made by pre-columbian technology

J Biener, MM Biener, RJ Madix, CM Friend - Acs catalysis, 2015 - ACS Publications
Nanoporous gold (np-Au), a three-dimensional nanoporous bulk material, is made by
selective corrosion of Ag from Ag–Au alloys, a technique already applied by the pre …

The Solvation-Induced Onsager Reaction Field Rather than the Double-Layer Field Controls CO2 Reduction on Gold

Q Zhu, SK Wallentine, GH Deng, JA Rebstock… - JACS Au, 2022 - ACS Publications
The selectivity and activity of the carbon dioxide reduction (CO2R) reaction are sensitive
functions of the electrolyte cation. By measuring the vibrational Stark shift of in situ …

Nanoporous Au: an unsupported pure gold catalyst?

A Wittstock, B Neumann, A Schaefer… - The Journal of …, 2009 - ACS Publications
The unique properties of gold especially in low temperature CO oxidation have been
ascribed to a combination of various effects. In particular, particle sizes below a few …