Since their development in the 1970s, cross-coupling reactions catalyzed by transition
metals have become one of the most important tools for constructing both carbon− carbon …

Enol and phenol functionalities are very common in organic molecules. Utilization of these
materials is very appealing in organic synthesis because they are important alternatives to …

This review draws a rather comprehensive picture of how Suzuki polycondensation was
discovered in 1989 and how it was subsequently developed into the most powerful …

Abstract Palladium-catalysed C (sp 2)–N cross-coupling (that is, Buchwald–Hartwig
amination) is employed widely in synthetic chemistry, including in the pharmaceutical …

Although palladium-catalyzed cross-coupling of aryl halides and reactive pseudohalides
has revolutionized the way organic molecules are constructed today across various fields of …

A catalytic system comprised of Pd (OAc) 2 and bidentate ligand dppe enabled first direct
arylations with moisture-stable aryl sulfamates as electrophiles, and proved applicable to …

A facile nickel-catalyzed method to achieve the amination of synthetically useful aryl
sulfamates and carbamates is reported. Contrary to most Ni-catalyzed amination reactions …

Aryl fluorosulfates are versatile building blocks in organic synthesis and have gained
increasing attention in SuFEx (Sulfur Fluoride Exchange) click chemistry. They are easily …

A nickel complex derived from dppf, along with NaO t-Bu as the base, allowed for
challenging aminations of aryl sulfamates. An improved functional group tolerance is …

How much fluoride is good for a strong electron‐withdrawing effect? In this review we
summarize recent results on the use of perfluoroalkanesulfonates, in particular of the cost …