Manipulating supramolecular gels with surfactants: Interfacial and non-interfacial mechanisms
Gel is a class of self-supporting soft materials with applications in many fields. Fast,
controllable gelation, micro/nano structure and suitable rheological properties are essential …
controllable gelation, micro/nano structure and suitable rheological properties are essential …
Architecture of supramolecular soft functional materials: From understanding to micro‐/nanoscale engineering
This article gives an overview of the current progress of a class of supramolecular soft
materials consisting of fiber networks and the trapped liquid. After discussing the up‐to‐date …
materials consisting of fiber networks and the trapped liquid. After discussing the up‐to‐date …
Solvent‐polarity‐tuned morphology and inversion of supramolecular chirality in a self‐assembled pyridylpyrazole‐linked glutamide derivative: nanofibers, nanotwists …
Q Jin, L Zhang, M Liu - Chemistry–A European Journal, 2013 - Wiley Online Library
The self‐assembly of a low‐molecular‐weight organogelator into various hierarchical
structures has been achieved for a pyridylpyrazole linked l‐glutamide amphiphile in different …
structures has been achieved for a pyridylpyrazole linked l‐glutamide amphiphile in different …
Comparing and correlating solubility parameters governing the self-assembly of molecular gels using 1, 3: 2, 4-dibenzylidene sorbitol as the gelator
Solvent properties play a central role in mediating the aggregation and self-assembly of
molecular gelators and their growth into fibers. Numerous attempts have been made to …
molecular gelators and their growth into fibers. Numerous attempts have been made to …
Solvent–gelator interactions—using empirical solvent parameters to better understand the self-assembly of gel-phase materials
W Edwards, CA Lagadec, DK Smith - Soft Matter, 2011 - pubs.rsc.org
By studying a family of L-lysine bis-urea gelators with variable peripheral groups in different
solvents, a more detailed understanding of the way in which gelator fibres interact with the …
solvents, a more detailed understanding of the way in which gelator fibres interact with the …
Dynamic Evolving Two-Component Supramolecular Gels Hierarchical Control over Component Selection in Complex Mixtures
W Edwards, DK Smith - Journal of the American Chemical Society, 2013 - ACS Publications
We report a two-component acid–amine gelation system which forms instant organogels on
simple mixing. We investigate self-assembly using a wide range of different amines and …
simple mixing. We investigate self-assembly using a wide range of different amines and …
Hansen solubility parameters as a tool in the quest for new edible oleogels
MA Rogers - Journal of the American Oil Chemists' Society, 2018 - Wiley Online Library
By identifying the Hansen space of nonfood‐grade gelators, which are capable of gelling oil,
insights into the molecular characteristics required for gelation of edible oil become …
insights into the molecular characteristics required for gelation of edible oil become …
Solvent effects on structure, photoresponse and speed of gelation of a dicholesterol-linked azobenzene organogel
By introducing methanol as a co-solvent into cyclopentanone, solvent effects on structure,
photoresponse and speed of gelation of a dicholesterol-linked azobenzene organogel …
photoresponse and speed of gelation of a dicholesterol-linked azobenzene organogel …
Tools for identifying gelator scaffolds and solvents
DM Zurcher, AJ McNeil - The Journal of Organic Chemistry, 2015 - ACS Publications
Small molecule gelators are serendipitously discovered more often than they are designed.
As a consequence, it has been challenging to develop applications based on the limited set …
As a consequence, it has been challenging to develop applications based on the limited set …
Estimation of organogel formation and influence of solvent viscosity and molecular size on gel properties and aggregate structures
H Xu, J Song, T Tian, R Feng - Soft Matter, 2012 - pubs.rsc.org
This paper proposes a simple method for predicting organogel formation, and highlights the
important role played by solvent viscosity (η) and molecular size (V) in influencing the gel …
important role played by solvent viscosity (η) and molecular size (V) in influencing the gel …