Conspectus Nickel excels at facilitating selective radical chemistry, playing a pivotal role in
metalloenzyme catalysis and modern cross-coupling reactions. Radicals, being nonpolar …

Transition-metal-catalyzed reductive coupling reactions have been considered as a
powerful tool to convert two electrophiles into value-added products. Numerous related …

Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …

Triplet ketone sensitizers are of central importance within the realm of photochemical
transformations. Although the radical-type character of triplet excited states of diaryl ketones …

The recent success of nickel catalysts in stereoconvergent cross-coupling and cross-
electrophile coupling reactions partly stems from the ability of monovalent nickel species to …

Mild methods to cleave the carbon-oxygen (C− O) bond in alkyl ethers could simplify
chemical syntheses through the elaboration of these robust, readily available precursors …

Self‐sustained NiI/III cycles are established as a potentially general paradigm in photoredox
Ni‐catalyzed carbon–heteroatom cross‐coupling reactions through a strategy that allows us …

Ni (I)-mediated single-electron oxidative activation of alkyl halides has been extensively
proposed as a key step in Ni-catalyzed cross-coupling reactions to generate radical …

The Ni-catalyzed Csp2–N cross-coupling of NH substrates and (hetero) aryl (pseudo)
halides for the synthesis of (hetero) anilines is in the midst of a resurgence. Reactivity …

Computational homogeneous catalysis has focused traditionally on the calculation of free
energy barriers, which are ultimately related to rate constants. Experiments do not focus on …