Spin crossover nanomaterials: from fundamental concepts to devices
Nanoscale spin crossover materials capable of undergoing reversible switching between
two electronic configurations with markedly different physical properties are excellent …
two electronic configurations with markedly different physical properties are excellent …
Molecular spin crossover phenomenon: recent achievements and prospects
A Bousseksou, G Molnár, L Salmon… - Chemical Society …, 2011 - pubs.rsc.org
Recently we assisted a strong renewed interest in the fascinating field of molecular spin
crossover complexes by (1) the emergence of nanosized spin crossover materials through …
crossover complexes by (1) the emergence of nanosized spin crossover materials through …
[HTML][HTML] Structural analysis of spin-crossover materials: From molecules to materials
E Collet, P Guionneau - Comptes Rendus Chimie, 2018 - Elsevier
In molecular spin-crossover materials, the spin-state switching is strongly coupled with
changes in the structural degrees of freedom, which play a central role in the alteration of …
changes in the structural degrees of freedom, which play a central role in the alteration of …
Spin transition charted in a fluorophore-tagged thermochromic dinuclear iron (II) complex
Y Garcia, F Robert, AD Naik, G Zhou… - Journal of the …, 2011 - ACS Publications
The first crystal structures of a dinuclear iron (II) complex with three N 1, N 2-1, 2, 4-triazole
bridges in the high-spin and low-spin states are reported. Its sharp spin transition, which was …
bridges in the high-spin and low-spin states are reported. Its sharp spin transition, which was …
Light-induced thermal hysteresis and high-spin low-spin domain formation evidenced by optical microscopy in a spin-crossover single crystal
The low-temperature photoinduced effects of the spin-crossover [{Fe (2-pytrz) 2 [Pd (CN) 4]}].
3 H 2 O single crystal have been investigated by means of a cryogenic optical microscopy …
3 H 2 O single crystal have been investigated by means of a cryogenic optical microscopy …
Tutorial on the elastic theory of spin crossover materials
AI Popa, L Stoleriu, C Enachescu - Journal of Applied Physics, 2021 - pubs.aip.org
In this paper, we present the ingredients that allow the building-up of the elastic model, one
of the approaches that successfully describes the phenomena observed in complex spin …
of the approaches that successfully describes the phenomena observed in complex spin …
General Landau theory of non-symmetry-breaking and symmetry-breaking spin transition materials
Spin-transition materials, including the families of spin-crossover and charge-transfer
systems, and more generally molecular-based materials exhibiting electronic and/or …
systems, and more generally molecular-based materials exhibiting electronic and/or …
Visualization and quantitative analysis of spatiotemporal behavior in a first-order thermal spin transition: A stress-driven multiscale process
We investigated by optical microscopy the propagation of the thermal spin transition in [Fe
(btr) 2 (NCS) 2]· H 2 O·(btr= bis-triazole) single crystals. Using high-quality fresh crystals …
(btr) 2 (NCS) 2]· H 2 O·(btr= bis-triazole) single crystals. Using high-quality fresh crystals …
Three-dimensional electroelastic modeling of the nucleation and propagation of the spin domains in spin-crossover materials
N Di Scala, NEI Belmouri, MAP Espejo… - Physical Review B, 2022 - APS
A three-dimensional version of the electroelastic model allowing the description of spin-
crossover (SCO) materials taking into account for the volume change at the transition …
crossover (SCO) materials taking into account for the volume change at the transition …
Hysteresis, nucleation and growth phenomena in spin-crossover solids
The observation and the study of first-order phase transitions in cooperative spin-crossover
(SCO) solids exhibiting hysteresis behaviours are of particular interest and currently …
(SCO) solids exhibiting hysteresis behaviours are of particular interest and currently …