Mechanochemistry–the utilization of mechanical forces to induce chemical reactions–is a
rarely considered tool for polymer synthesis. It offers numerous advantages such as reduced …

Direct mechanocatalysis (DM) describes solvent-free catalytic reactions that are initiated by
mechanical forces in mechanochemical reactors such as ball mills. The distinctive feature of …

It is shown that corannulene‐based strained π‐surfaces can be obtained through the use of
mechanochemical Suzuki and Scholl reactions. Besides being solvent‐free, the …

Hypercrosslinked polymers (HCPs) are typically synthesised over 24 hour batch reactions,
limiting productivity rates during scale-up production. Continuous flow synthesis can …

Hyper-cross-linked polymers (HCPs) are receiving great attention due to their high specific
surface areas, allowing them to offer high performances in many different applications …

Although hydrogen is a promising energy carrier to replace fossil fuels and reduce CO 2
emissions, its low volumetric energy density remains a major drawback. Indeed, hydrogen …

Designable porous materials have potential in a plethora of applications, but synthesis costs
and strict reaction conditions limit their true commercialization. Herein, we show that …

Herein we report the mechanochemical Scholl polymerization of 1, 3, 5-triphenylbenzene in
a high speed ball mill. The reaction is conducted solvent-free, solely using solid FeCl3. The …

Herein we report the mechanochemical Friedel‐Crafts alkylation of 1, 3, 5‐triphenylbenzene
(TPB) with two organochloride cross‐linking agents, dichloromethane (DCM) and chloroform …

We evaluated the potential of several novel porous materials for toluene capture in air under
humid conditions. Four novel porous solids of different nature were studied and compared to …