There are mechanistic dichotomies with regard to the formation, electronic structures and
reaction mechanisms of metal–oxygen intermediates, since these metal–oxygen species …

Copper complexes are highly versatile species that find promising uses in broad fields such
as catalysis, drug design, and bioinorganic applications. However, copper complexes …

The catalytic activation of peroxymonosulfate (PMS) is under intensive investigation with
potentials as an alternative advanced oxidation process (AOP) in wastewater treatment …

In controlled radical polymerization, oxygen is typically regarded as an undesirable
component resulting in terminated polymer chains, deactivated catalysts, and subsequent …

We report the first literature example using visible light-induced trimethylsilyl azide (TMS-N3)-
assisted copper-catalyzed oxy-sulfonylation of terminal CC bonds to form β-keto sulfones (C …

Changes in the electronic structure of copper complexes can have a remarkable impact on
the catalytic rates, selectivity, and overpotential of electrocatalytic reactions. We have …

This review summarizes the latest discoveries in the field of C–H activation by copper
monoxygenases and more particularly by their bioinspired systems. This work first describes …

Metalloproteins perform a diverse array of redox-related reactions facilitated by the
increased chemical functionality afforded by their metallocofactors. Lytic polysaccharide …

In this report, we investigate the physical and chemical properties of monocopper Cu (I)
superoxo and Cu (II) peroxo and hydroperoxo complexes. These are prepared by …

The use of the in situ generated ligand–copper superoxo complex absorbing light energy to
activate the alpha C (sp3)–H of MeOH and EtOH via the hydrogen atom transfer (HAT) …