Reactivity of Aluminum Cluster Anions with Water: Origins of Reactivity and Mechanisms for H2 Release
The reactivity of aluminum anion clusters with water was found to exhibit variations with size,
with some clusters exhibiting negligible reactivity, others absorbing one or more water, while …
with some clusters exhibiting negligible reactivity, others absorbing one or more water, while …
Functionalization of nine-atom deltahedral Zintl ions with organic substituents: detailed studies of the reactions
MW Hull, SC Sevov - Journal of the American Chemical Society, 2009 - ACS Publications
Presented are the results of a systematic investigation of the reactions of nine-atom
deltahedral clusters of germanium (Zintl ions, Ge9 n−) with alkynes and alkyl halides that …
deltahedral clusters of germanium (Zintl ions, Ge9 n−) with alkynes and alkyl halides that …
A Computational Exploration of Exohedrally Transition Metal Doped Si94– Superatom Based Magnetic MSi9M′ Clusters (M, M′ = Sc(II) to Cu(II))
Nanosized clusters are drawing immense attention of the scientific community due to their
size and composition dependent tunability of physical and chemical properties. Silicon …
size and composition dependent tunability of physical and chemical properties. Silicon …
Bismuth-doped Tin clusters: experimental and theoretical studies of neutral Zintl analogues
S Heiles, RL Johnston, R Schäfer - The Journal of Physical …, 2012 - ACS Publications
The electron count of gas-phase clusters is increased gradually by element substitution in
order to mimic the total number of electrons of known stable closo-clusters. A combination of …
order to mimic the total number of electrons of known stable closo-clusters. A combination of …
Structural Evolution of Gold-Doped Bismuth Clusters AuBin– (n = 4–8)
The structures of gold-doped bismuth clusters, AuBi n–(n= 4–8), are investigated through a
joint photoelectron spectroscopy and density functional theory (DFT) study. Well-resolved …
joint photoelectron spectroscopy and density functional theory (DFT) study. Well-resolved …
Photoelectron Spectroscopy of BiAu– and BiBO–: Further Evidence of the Analogy between Au and Boronyl
Boronyl (BO) is a monovalent σ radical with a B O triple bond. Its chemistry has remained
relatively unknown, though analogy has been established for BO with monovalent atoms …
relatively unknown, though analogy has been established for BO with monovalent atoms …
Photoelectron spectroscopic and computational studies of the and anions
A Grubisic, H Wang, X Li, YJ Ko… - Proceedings of the …, 2011 - National Acad Sciences
A combination of anion photoelectron spectroscopy and density functional theory
calculations has elucidated the geometric and electronic structure of gas-phase endohedral …
calculations has elucidated the geometric and electronic structure of gas-phase endohedral …
[HTML][HTML] Electronic structure, stability, and oxidation of boron-magnesium clusters and cluster solids
Electronic structure studies on Mg m B n−(1≤ n≤ 15, 0≤ m≤ 3) clusters have been
performed to identify the nature of bonding and the origin of stability in the mixed clusters …
performed to identify the nature of bonding and the origin of stability in the mixed clusters …
Combined Experimental and Theoretical Study of AlnX (n = 1−6; X = As, Sb) Clusters: Evidence of Aromaticity and the Jellium Model
JJ Melko, PA Clayborne, CE Jones Jr… - The Journal of …, 2010 - ACS Publications
The electronic structure of Al n X (n= 1− 6; X= As, Sb) clusters has been investigated using a
synergistic approach combining negative ion photoelectron spectroscopy and first principles …
synergistic approach combining negative ion photoelectron spectroscopy and first principles …
Substituent-dependent exchange mechanisms in highly fluxional RSn 9 3− anions
FS Kocak, PY Zavalij, YF Lam… - Chemical communications, 2009 - pubs.rsc.org
Substituent-dependent exchange mechanisms in highly fluxional RSn 9 3 − anions - Chemical
Communications (RSC Publishing) DOI:10.1039/B905239A Royal Society of Chemistry View …
Communications (RSC Publishing) DOI:10.1039/B905239A Royal Society of Chemistry View …