Reactivity of Aluminum Cluster Anions with Water: Origins of Reactivity and Mechanisms for H2 Release

AC Reber, SN Khanna, PJ Roach… - The Journal of …, 2010 - ACS Publications
The reactivity of aluminum anion clusters with water was found to exhibit variations with size,
with some clusters exhibiting negligible reactivity, others absorbing one or more water, while …

Functionalization of nine-atom deltahedral Zintl ions with organic substituents: detailed studies of the reactions

MW Hull, SC Sevov - Journal of the American Chemical Society, 2009 - ACS Publications
Presented are the results of a systematic investigation of the reactions of nine-atom
deltahedral clusters of germanium (Zintl ions, Ge9 n−) with alkynes and alkyl halides that …

A Computational Exploration of Exohedrally Transition Metal Doped Si94– Superatom Based Magnetic MSi9M′ Clusters (M, M′ = Sc(II) to Cu(II))

A Mandal, T Goswami… - The Journal of Physical …, 2023 - ACS Publications
Nanosized clusters are drawing immense attention of the scientific community due to their
size and composition dependent tunability of physical and chemical properties. Silicon …

Bismuth-doped Tin clusters: experimental and theoretical studies of neutral Zintl analogues

S Heiles, RL Johnston, R Schäfer - The Journal of Physical …, 2012 - ACS Publications
The electron count of gas-phase clusters is increased gradually by element substitution in
order to mimic the total number of electrons of known stable closo-clusters. A combination of …

Structural Evolution of Gold-Doped Bismuth Clusters AuBin (n = 4–8)

S Pande, T Jian, NS Khetrapal, LS Wang… - The Journal of …, 2018 - ACS Publications
The structures of gold-doped bismuth clusters, AuBi n–(n= 4–8), are investigated through a
joint photoelectron spectroscopy and density functional theory (DFT) study. Well-resolved …

Photoelectron Spectroscopy of BiAu and BiBO: Further Evidence of the Analogy between Au and Boronyl

T Jian, GV Lopez, LS Wang - The Journal of Physical Chemistry B, 2016 - ACS Publications
Boronyl (BO) is a monovalent σ radical with a B O triple bond. Its chemistry has remained
relatively unknown, though analogy has been established for BO with monovalent atoms …

Photoelectron spectroscopic and computational studies of the and anions

A Grubisic, H Wang, X Li, YJ Ko… - Proceedings of the …, 2011 - National Acad Sciences
A combination of anion photoelectron spectroscopy and density functional theory
calculations has elucidated the geometric and electronic structure of gas-phase endohedral …

[HTML][HTML] Electronic structure, stability, and oxidation of boron-magnesium clusters and cluster solids

AC Reber, SN Khanna - The Journal of Chemical Physics, 2015 - pubs.aip.org
Electronic structure studies on Mg m B n−(1≤ n≤ 15, 0≤ m≤ 3) clusters have been
performed to identify the nature of bonding and the origin of stability in the mixed clusters …

Combined Experimental and Theoretical Study of AlnX (n = 1−6; X = As, Sb) Clusters: Evidence of Aromaticity and the Jellium Model

JJ Melko, PA Clayborne, CE Jones Jr… - The Journal of …, 2010 - ACS Publications
The electronic structure of Al n X (n= 1− 6; X= As, Sb) clusters has been investigated using a
synergistic approach combining negative ion photoelectron spectroscopy and first principles …

Substituent-dependent exchange mechanisms in highly fluxional RSn 9 3− anions

FS Kocak, PY Zavalij, YF Lam… - Chemical communications, 2009 - pubs.rsc.org
Substituent-dependent exchange mechanisms in highly fluxional RSn 9 3 − anions - Chemical
Communications (RSC Publishing) DOI:10.1039/B905239A Royal Society of Chemistry View …