A simple and versatile amide directing group for C− H functionalizations

RY Zhu, ME Farmer, YQ Chen… - Angewandte Chemie …, 2016 - Wiley Online Library
Achieving selective C− H activation at a single and strategic site in the presence of multiple
C− H bonds can provide a powerful and generally useful retrosynthetic disconnection. In this …

Transition Metal Promoted Cascade Heterocycle Synthesis through C− H Functionalization

A Baccalini, G Faita, G Zanoni… - Chemistry–A European …, 2020 - Wiley Online Library
Sequential, domino and tandem reactions could be defined as a sequence of synthetic
transformations that occur one after the other, in the same reaction flask. This Review …

Cobalt‐Catalyzed Oxidative Annulation of Nitrogen‐Containing Arenes with Alkynes: An Atom‐Economical Route to Heterocyclic Quaternary Ammonium Salts

S Prakash, K Muralirajan, CH Cheng - Angewandte Chemie, 2016 - Wiley Online Library
Four cobalt‐catalyzed oxidative annulation reactions of nitrogen‐containing arenes with
alkynes proceeds by C− H activation, thus leading to biologically useful quaternary …

Cyclopentadienyl complexes of group 9 metals in the total synthesis of natural products

VB Kharitonov, DV Muratov, DA Loginov - Coordination Chemistry Reviews, 2022 - Elsevier
Organic transformations catalyzed by cyclopentadienyl complexes of Group 9 metals (cobalt,
rhodium and iridium) are the key steps of the total synthesis of various natural products …

Easy Access to 1‐Amino and 1‐Carbon Substituted Isoquinolines via Cobalt‐Catalyzed CH/NO Bond Activation

K Muralirajan, R Kuppusamy… - … Synthesis & Catalysis, 2016 - Wiley Online Library
A green atom‐economical method for the synthesis of highly functionalized 1‐amino and 1‐
carbon substituted isoquinolines from the reaction of N′‐hydroxybenzimidamides and aryl …

Rh (III)-catalyzed and solvent-controlled chemoselective synthesis of chalcone and benzofuran frameworks via synergistic dual directing groups enabled …

W Yi, W Chen, FX Liu, Y Zhong, D Wu, Z Zhou… - ACS …, 2018 - ACS Publications
By virtue of a synergistically dual-directing-group (the O–NHAc part and the hydroxyl group)-
assisted strategy, the efficient and practical Rh (III)-catalyzed regioselective redox-neutral C …

Eine einfache und vielseitige dirigierende Amidgruppe zur Funktionalisierung von C‐H‐Bindungen

RY Zhu, ME Farmer, YQ Chen, JQ Yu - Angewandte Chemie, 2016 - Wiley Online Library
Abstract Die selektive C‐H‐Aktivierung an einer einzigen und strategisch wichtigen Position
in Gegenwart von zahlreichen weiteren C‐H‐Bindungen kann einen leistungsfähigen und …

[PDF][PDF] Research advances in CH bond activation of multitasking N-phenoxyamides

Y Zhu, X Zhao, Q Wu, Y Chen, J Zhao - Wuli Huaxue Xuebao, 2019 - whxb.pku.edu.cn
Transition-metal-catalyzed C―H functionalization reactions, assisted by directing groups
(DGs), have become some of the most powerful strategies to form C―C and C―X (X= O, N …

N‐Methoxybenzamide: A Versatile Directing Group for Palladium‐, Rhodium‐ and Ruthenium‐Catalyzed C−H Bond Activations

DD Subhedar, AA Mishra… - Advanced Synthesis & …, 2019 - Wiley Online Library
The C− H bond activation reactions catalyzed by a transition metal have always been a topic
of intense research. Although the incorporation or removal of a directing group plays an …

Hydroxyl Group‐Prompted and Iridium(III)‐Catalyzed Regioselective C−H Annulation of N‐phenoxyacetamides with Propargyl Alcohols

W Chen, FX Liu, W Gong, Z Zhou, H Gao… - Advanced Synthesis …, 2018 - Wiley Online Library
An efficient, mild and redox‐neutral iridium (III)‐catalyzed C− H annulation of N‐
phenoxyacetamides for the regioselective synthesis of benzofurans has been developed by …