Boron-containing compounds (BCC) have emerged as important pharmacophores. To date,
five BCC drugs (including boronic acids and boroles) have been approved by the FDA for …

Conspectus Organoboron compounds are a class of multifunctional reagents for the
construction of carbon–carbon and carbon–heteroatom bonds in modern synthetic …

Enantioenriched organoboron intermediates are important building blocks in organic
synthesis and drug discovery. Recently, transition metal-catalyzed enantioselective 1, 2 …

The construction of acyclic, non‐adjacent 1, 3‐stereogenic centers, prevalent motifs in drugs
and bioactive molecules, has been a long‐standing synthetic challenge due to acyclic …

Abstract In recent years, numerous 1, 2-R shift (R= aliphatic or aryl) based on
tetracoordinate boron species have been well investigated. In the contrary, the …

Nucleic acids, with the advantages of programmability and biocompatibility, have been
widely used to design different kinds of novel biocomputing devices. Recently, nucleic acid …

Asymmetric cross‐couplings based on 1, 2‐carbon migration from B‐ate complexes have
been developed efficiently to access valuable organoboronates. However, enantioselective …

Bis‐boronic esters are useful synthetic intermediates particularly as the two boronic esters
can be selectively functionalized. Usually, the less hindered primary boronic ester reacts, but …

Compared with the well-developed centrally chiral boron chemistry, C–B axially chiral
chemistry remains elusive and challenging. Herein we report the first atroposelective …

Operationally simple strategies to assemble boron containing organic frameworks are highly
enabling in organic synthesis. While conventional retrosynthetic logic has engendered many …