[HTML][HTML] Sandwich d/f Heterometallic Complexes [(Ln(hfac)3)2M(acac)3] (Ln = La, Pr, Sm, Dy and M = Co; Ln = La and M = Ru)

C Grechi, S Carlotto, M Guelfi, S Samaritani, L Armelao… - Molecules, 2024 - mdpi.com
Sandwich d/f heterometallic complexes [(Ln (hfac) 3) 2M (acac) 3](Ln= La, Pr, Sm, Dy and
M= Co; Ln= La and M= Ru) were prepared in strictly anhydrous conditions reacting the …

Heterometallic Rare-Earth Complexes: A Review on Magnetism, Catalysis and Transformation to Nanomaterials

R Petrus, A Kowaliński - 2024 - preprints.org
Heterometallic rare-earth clusters have garnered much attention because of their interest-
ing solid-state structures and versatile applications in catalysis and material and polymer …

Construction of A sqc6 Topology Ni‐Gd Framework Employing 2,2'‐Phosphinico‐dibenzoate and Oxalate: Structure and Magnetic Properties

N Tan, WG Chen, P Wu… - Zeitschrift für anorganische …, 2023 - Wiley Online Library
A 3d–4f heterometallic compound, namely [Ni6GdL4 (ox)(H2O) 12]⋅[NO3]⋅ 14.5 H2O
(1)(L= 2, 2'‐phosphinico‐dibenzoate and ox= oxalate), was obtained by self‐assembly of …

Design and synthesis of a new family of the decanuclear Mn− Ln clusters: A novel approach to nonlinear optical molecular functional materials

D Shi, Y He, CJ Zhao, F Xu - Journal of Solid State Chemistry, 2024 - Elsevier
For the first time, the {Mn 5 Ln 5}(Ln= Sm (1), Eu (2), Gd (3), Dy (4) and Tb (5)) clusters were
synthesized via a one-pot approach utilizing 2-amino-2-methyl-1.3-propanediol as the …

The Complexation in Co(NO3)2 ⋅ 6H2O/2,2′‐bipyridine/Y(NO3)3 ⋅ 6H2O/MeOH System: Still More to Uncover

A Gavrikov, M Buzoverov, K Babeshkin… - … für anorganische und …, 2024 - Wiley Online Library
The formation of novel uncommon heterodinuclear complex was detected in Co (NO3) 2⋅
6H2O/2, 2′‐bipyridine/Y (NO3) 3⋅ 6H2O/MeOH system. The peculiarities of composition …

[HTML][HTML] UFO-shaped heteronuclear 3d–4f metal clusters: Synthesis, structure, and magnetic properties

H Zhang, CK Li, J Liu, ZB Wang, LY Liu, ZX Lu… - Results in …, 2023 - Elsevier
Coordination molecule clusters assembled from a large number of metal ions and organic
ligands are structurally and functionally challenging to characterize. Here, a series of new …