Dynamic covalent chemistry (DCC) focuses on the reversible formation, breakage, and
exchange of covalent bonds and assemblies, setting a bridge between irreversible organic …

In recent years, intramolecular noncovalent interaction has become an important means to
modulate the optoelectronic performances of organic/polymeric semiconductors. However, it …

Conspectus London forces constitute an attractive component of van der Waals interactions
and originate from transient correlated momentary dipoles in adjacent atoms. The in-depth …

The formal C–H bond insertion reaction into aldehydes via 1, 2-hydride shift has been well
established; however, the formal C–C bond insertion is more challenging. In the presence of …

The chemical synthesis of molecules with closely packed atoms having their bond
coordination saturated is a challenge to synthetic chemists, especially when three …

Stabilizing nitrogen pnictogen bond interactions were measured using molecular rotors.
Intramolecular C= O⋅⋅⋅ N interactions were formed in the bond rotation transition states …

We report the direct observation of tetrel bonding interactions between sp3-carbons of the
supramolecular synthon 3, 3-dimethyl-tetracyanocyclopropane (1) and tetrahydrofuran in the …

Noncovalent interactions between a lone pair of electrons and π systems can be
categorized into two types based on the nature of π systems. Lone pair− π (C═ O) …

The imine bond holds a prominent place in supramolecular chemistry and materials science,
and one issue is the stability of imines due to their electrophilic nature. Here we introduced …

Herein, a perspective on the recent understanding of weak n→ π* interaction obtained using
different experimental and theoretical approaches is presented. This interaction is purely an …