The chemistry of the carbon-transition metal double and triple bond: annual survey covering the year 2016

JW Herndon - Coordination Chemistry Reviews, 2018 - Elsevier
This is a review of papers published in the year 2016 that focus on the synthesis, reactivity,
or properties of compounds containing a carbon-transition metal double or triple bond …

The use of [2-C6R4PPh2]−(R= H, F) and related carbanions as building blocks in coordination chemistry

MA Bennett, SK Bhargava, N Mirzadeh… - Coordination Chemistry …, 2018 - Elsevier
Over the last half-century, aryl carbanions of the general type [2-C 6 R 4 ER′ 2]−(R= H, F;
E= Group 15 element; R′= various alkyl and aryl groups) have found increasing application …

Ligation state of nickel during CO bond activation with monodentate phosphines

LV Hooker, SR Neufeldt - Tetrahedron, 2018 - Elsevier
The oxidative addition of phenolic electrophiles at Ni (0) in the presence of monodentate
phosphine ligands was studied with both dispersion-free and dispersion-containing DFT …

Improving a Methane C–H Activation Complex by Metal and Ligand Alterations from Computational Results

DB Ninković, S Moncho, P Petrović, MB Hall… - Inorganic …, 2023 - ACS Publications
We present results for a series of complexes derived from a titanium complex capable of
activating C–H bonds under mild conditions (PNP) Ti═ CH t Bu (CH2 t Bu), where PNP= N …

Aromatic Substitution

MR Crampton - … Reaction Mechanisms· 2017: An annual survey …, 2020 - Wiley Online Library
Summary This Chapter Contains Sections titled: Introduction General Nucleophilic
Substitution The S NAr Mechanism Meisenheimer and Related Complexes Benzyne and …

Recent computational studies on transition‐metal carbon–hydrogen bond activation of alkanes

J Guan, SD Zarić, EN Brothers… - International Journal of …, 2018 - Wiley Online Library
This review on computational studies of transition‐metal promoted C H activation of light
linear alkanes will cover computational work published since 2010, following upon seminal …

Methane Activations by Titanium Neopentylidene Complexes: electronic resilience and steric control

DB Ninković, S Moncho, PV Petrović, SD Zarić… - Inorganic …, 2017 - ACS Publications
The titanium neopentylidene complex (PNP) Ti CHtBu (CH2tBu)(PNP= N [2-PiPr2-4-
methylphenyl] 2–) is capable of activating both sp2 and sp3 C–H bonds under mild …