A new protocol for photochemical perfluoroalkylation reactions using perfluoroalkyl iodide,
amine additive, and THF solvent is reported. This protocol does not require a photoredox …

Recent protocols and reactions for catalytic radical perfluoroalkylations will be described.
The production of perfluoroalkyl radicals (RF= C n F2 n+ 1, n≥ 2), which effect both addition …

A selection of perfluoroalkylation reactions of aliphatic substrates that display
methodological and synthetic amplitude will be studied, giving examples of their …

The aim of this review is to provide a comprehensive overview of the direct
trifluoromethylation of olefinic C–H bonds with special attention on the mechanistic aspects …

Perfluoroalkylation reactions of arenes have not been the subject of intense study as has
been the case for the trifluoromethylation reactions of aromatics. However, the new synthetic …

Fluorination of styrene derivatives with a reagent system composed of μ-oxo-bis
[trifluoroacetato (phenyl) iodine] and a pyridine· HF complex gave the corresponding (2, 2 …

A tunable chemoselective trifluoromethanesulfonylation and trifluoromethylation of
arenediazonium tetrafluoroborates with Langlois' reagent (NaSO2CF3) was developed. The …

9-(2, 6-Dimethylphenyl)-10-methylacridinium perchlorate ([Acr+–Xyl] ClO4–), 9-(4-chloro-2,
6-dimethylphenyl)-10-methylacridinium perchlorate ([Acr+–XylCl] ClO4–), and 9-(4-fluoro-2 …

The introduction of trifluoroalkyl groups into aromatic molecules is an important
transformation in the field of organic and medicinal chemistry. However, the direct …

A visible light-induced selective hydrobromodifluoromethylation of alkenes using CF2Br2
was developed. This transformation proceeded smoothly in the presence of catalytic eosin Y …