Catalytic cross-coupling reactions of aromatic esters and amides have recently gained
considerable attention from synthetic chemists as de novo and efficient synthetic methods to …

Transition-metal-catalyzed decarbonylation via carbon–carbon bond cleavage is an
essential synthetic methodology. Given the ubiquity of carbonyl compounds, the selective …

Metal-catalyzed cross-couplings represent one of the most important reaction platforms in
modern synthetic chemistry (Figure 1 A). 1 Although the field enjoys a rich history, there …

The development and application of efficient, convenient, selective, and environmentally
benign synthetic methods is highly desirable in organic chemistry. With this requirement …

This critical review examines transition metal-catalyzed decarboxylative couplings that have
emerged within recent years as a powerful strategy to form carbon–carbon or carbon …

Metal‐catalyzed reactions of amides proceeding via metal insertion into the N CO bond
are severely underdeveloped due to resonance stabilization of the amide bond. Herein we …

In organic molecules carboxylic acid groups are among the most common functionalities.
Activated derivatives of carboxylic acids have long served as versatile connection points in …

This tutorial review provides a comparison between the concepts of catalytic decarboxylative
and decarbonylative couplings for the ipso-substitution of carboxylate groups, and illustrates …

The Suzuki–Miyaura coupling is among the most important C–C bond-forming reactions
available due to its reliability, chemoselectivity, and diversity. Aryl halides and …

The development of a palladium-catalyzed decarboxylative coupling reaction of arene
carboxylates with olefinic substrates is described. The optimized procedure for …