Cycloaddition reactions of o-quinone methides with polarized olefins

VA Osyanin, AV Lukashenko… - Russian Chemical …, 2021 - iopscience.iop.org
The review summarizes and systematizes the [4+ 2]-cycloaddition reactions of o-quinone
methides with electron-rich and electron-deficient olefins. The electron-rich substrates …

Methods for metal and non-metal catalyzed synthesis of six-membered oxygen containing poly-heterocycles

N Kaur - Current Organic Synthesis, 2017 - ingentaconnect.com
In recent decades, a large number of reports related to synthesis of N, O and S containing
heterocycles have appeared owing to a wide variety of their biological activity. We need a …

Comparative evaluation of substituent effect on the photochromic properties of spiropyrans and spirooxazines

EI Balmond, BK Tautges, AL Faulkner… - The Journal of …, 2016 - ACS Publications
Spiropyrans and spirooxazines represent an important class of photochromic compounds
with a wide variety of applications. In order to effectively utilize and design these …

Generation and Application of o‐Quinone Methides Bearing Various Substituents on the Benzene Ring

H Sugimoto, S Nakamura… - Advanced Synthesis & …, 2007 - Wiley Online Library
Abstract o‐Quinone methides (o‐QMs) are highly reactive, short‐lived intermediates, which
have potential synthetic applicability. However, few studies on the generation of o‐QMs …

[PDF][PDF] Synthesis of 1, 2-oxazines and their N-oxides

PG Tsoungas - Heterocycles-Sendai Institute of …, 2002 - triggered.stanford.clockss.org
THE SYNTHESIS OF 1,2-OXAZINES AND THEIR N-OXIDES Page 1 HETEROCYCLES, Vol.
57, No. 6, 2002, pp. 1149-1178, Received, 6th February, 2002 SYNTHESIS OF 1,2-OXAZINES …

A facile approach to synthesize 3, 5-disubstituted-1, 2, 4-oxadiazoles via copper-catalyzed-cascade annulation of amidines and methylarenes

W Guo, K Huang, F Ji, W Wu, H Jiang - Chemical Communications, 2015 - pubs.rsc.org
Various 3, 5-disubstituted-1, 2, 4-oxadiazoles are smoothly formed via copper-catalyzed
cascade annulation of amidines and methylarenes. This tandem oxidation–amination …

Synthesis of Isoxazoline N-Oxides via [Hydroxy(tosyloxy)iodo]benzene (HTIB)-Mediated Oxidative N−O Coupling

MJ Raihan, V Kavala, PM Habib, QZ Guan… - The Journal of …, 2011 - ACS Publications
An HTIB mediated oxidative N− O coupling strategy for the synthesis of some isoxazoline N-
oxide derivatives from β-hydroxyketoximes is described, along with a comparative study of …

Retro-Diels−Alder Reaction of 4H-1,2-Benzoxazines to Generate o-Quinone Methides:  Involvement of Highly Polarized Transition States

H Sugimoto, S Nakamura… - The Journal of Organic …, 2007 - ACS Publications
Here, we describe mechanistic studies of the retro-Diels− Alder reaction of 4 H-1, 2-
benzoxazines bearing various substituents on the benzene ring. 4 H-1, 2-Benzoxazines are …

[PDF][PDF] 1, 2-Oxazines and their N-oxides in synthesis

PG Tsoungas - Heterocycles-Sendai Institute of …, 2002 - triggered.stanford.clockss.org
1,2-OXAZINES AND THEIR N-OXIDES IN SYNTHESIS Petros G. Tsoungas Ministry of
Development, Department of Research and Technology, Page 1 HETEROCYCLES, Vol. 57, No …

Self Cycloaddition of o‐Naphthoquinone Nitrosomethide to (±) Spiro{naphthalene(naphthopyranofurazan)}‐one Oxide: An Insight into its Formation

D Tzeli, IE Gerontitis, ID Petsalakis… - …, 2022 - Wiley Online Library
Hydroxy‐1‐naphthaldehyde oxime was oxidized by AgO (or Ag2O), in presence of N‐methyl
morpholine N‐oxide (NMMO), to the title spiro adduct‐dimer (±)‐Spiro {naphthalene‐1 (2H) …