Open-shell molecules such as radicals, carbenes, and electronically excited-state molecules
exhibit high energies, and thus, in general, they are quite reactive. 1 The short-lived species …

Reactivity and physical properties of p-conjugated hydrocarbon systems depend
predominantly on the topology of p-electrons array. Quinoidal conjugations serve as giving …

High‐spin conjugated radicals have great potential in magnetic materials and organic
spintronics. However, to obtain high‐spin conjugated radicals is still quite challenging due to …

Reactions of a benzo [e][1, 2, 4] triazine with dilithiobenzenes lead to di‐Blatter diradicals
connected at the N (1) positions via a spin coupling unit, 1, 4‐phenylene or 1, 3‐phenylene …

Diradicals have been of tremendous interest for over a century ever since the first reports of
p‐and m‐phenylene‐bridged diphenylmethylradicals in 1904 by Thiele and 1915 by …

Meta-benzoquinodimethane (MBQDM) or m-xylylene provides a model for larger organic
diradicals, the triplet–singlet gap being the key property. In the present work this energy …

We begin by reviewing the early developments in the synthesis of high-spin organic
molecules and the simultaneous rationalization of the ground states of high spin. A number …

Organic materials with extraordinary magnetic properties promise a wide range of light,
flexible, and inexpensive alternatives to familiar metal-based magnets. Individual organic …

In this review, rational design strategies for pure organic high‐spin molecules with strong
intramolecular magnetic interactions are presented, mostly focusing on the design of …

A modular approach for the synthesis of isolable crystalline Schlenk hydrocarbon diradicals
from m‐phenylene bridged electron‐rich bis‐triazaalkenes as synthons is reported. EPR …