3d transition metals for C–H activation
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …
notable applications to material sciences, crop protection, drug discovery, and …
Recent Advances in Mn, Fe, Co, and Ni-Catalyzed Organic Reactions
This paper reviewed the recent research progress of organic reactions catalyzed by four
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …
Electrochemical C− H/N− H activation by water‐tolerant cobalt catalysis at room temperature
Abstract Electrochemistry enabled C− H/N− H functionalizations at room temperature by
external oxidant‐free cobalt catalysis. Thus, the sustainable cobalt electrocatalysis manifold …
external oxidant‐free cobalt catalysis. Thus, the sustainable cobalt electrocatalysis manifold …
Electroremovable traceless hydrazides for cobalt-catalyzed electro-oxidative C–H/N–H activation with internal alkynes
R Mei, N Sauermann, JCA Oliveira… - Journal of the American …, 2018 - ACS Publications
Electrochemical oxidative C–H/N–H activations have been accomplished with a versatile
cobalt catalyst in terms of [4+ 2] annulations of internal alkynes. The electro-oxidative C–H …
cobalt catalyst in terms of [4+ 2] annulations of internal alkynes. The electro-oxidative C–H …
Cobalt‐Catalyzed Annulation Reactions via C− H Bond Activation
Considerable research attention has been directed towards the use of first‐row transition
metals in organic synthesis. The more abundant, and less expensive cobalt is considered to …
metals in organic synthesis. The more abundant, and less expensive cobalt is considered to …
Recent advances using [Cp* Co (CO) I 2] catalysts as a powerful tool for C–H functionalisation
PG Chirila, CJ Whiteoak - Dalton Transactions, 2017 - pubs.rsc.org
Expansion of the synthetic chemists' toolbox is currently a topic of great interest, with
successes providing access to novel compounds and more efficient routes towards new and …
successes providing access to novel compounds and more efficient routes towards new and …
Carboxylate-Assisted Formation of Aryl-Co (III) Masked-Carbenes in Cobalt-Catalyzed C–H Functionalization with Diazo Esters
O Planas, S Roldan-Gomez… - Journal of the …, 2017 - ACS Publications
Herein we describe the synthesis of a family of aryl-Co (III)-carboxylate complexes and their
reactivity with ethyl diazoacetate. Crystallographic, full spectroscopic characterization, and …
reactivity with ethyl diazoacetate. Crystallographic, full spectroscopic characterization, and …
Cobalt‐Catalyzed Coupling of Benzoic Acid C− H Bonds with Alkynes, Styrenes, and 1, 3‐Dienes
TT Nguyen, L Grigorjeva… - Angewandte Chemie …, 2018 - Wiley Online Library
A method for cobalt‐catalyzed, carboxylate‐directed functionalization of arene C− H bonds
is reported. Alkynes, styrenes, and 1, 3‐dienes can be coupled with benzoic acids to provide …
is reported. Alkynes, styrenes, and 1, 3‐dienes can be coupled with benzoic acids to provide …
A Unified Electro- and Photocatalytic CO2 to CO Reduction Mechanism with Aminopyridine Cobalt Complexes
S Fernández, F Franco, C Casadevall… - Journal of the …, 2019 - ACS Publications
A mechanistic understanding of electro-and photocatalytic CO2 reduction is crucial to
develop strategies to overcome catalytic bottlenecks. In this regard, for a new CO2-to-CO …
develop strategies to overcome catalytic bottlenecks. In this regard, for a new CO2-to-CO …
Insights into Cobalta (III/IV/II)‐Electrocatalysis: Oxidation‐Induced Reductive Elimination for Twofold C− H Activation
The merger of cobalt‐catalyzed C− H activation and electrosynthesis provides new avenues
for resource‐economical molecular syntheses, unfortunately their reaction mechanisms …
for resource‐economical molecular syntheses, unfortunately their reaction mechanisms …