Thiomolybdate clusters: from homogeneous catalysis to heterogenization and active sites
S Batool, M Langer, SN Myakala, M Heiland… - Advanced …, 2024 - Wiley Online Library
Thiomolybdates are molecular molybdenum‐sulfide clusters formed from Mo centers and
sulfur‐based ligands. For decades, they have attracted the interest of synthetic chemists due …
sulfur‐based ligands. For decades, they have attracted the interest of synthetic chemists due …
A Mild and Chemoselective Reduction of Nitro and Azo Compounds Catalyzed by a Well‐Defined Mo3S4 Cluster Bearing Diamine Ligands
E Pedrajas, I Sorribes, K Junge, M Beller… - …, 2015 - Wiley Online Library
Herein, we report a novel well‐defined diamino Mo3S4‐based catalyst system for the
reduction of nitroarenes and azo compounds to the corresponding anilines with silanes as …
reduction of nitroarenes and azo compounds to the corresponding anilines with silanes as …
Enhanced performance of NaTaO 3 using molecular co-catalyst [Mo 3 S 4] 4+ for water splitting into H 2 and O 2
Enhanced performance of NaTaO 3 using molecular co-catalyst [Mo 3 S 4 ] 4+ for water
splitting into H 2 and O 2 - Chemical Communications (RSC Publishing) DOI:10.1039/C2CC36216C …
splitting into H 2 and O 2 - Chemical Communications (RSC Publishing) DOI:10.1039/C2CC36216C …
Phosphorescent Complexes of {Mo6I8}4+ and {W6I8}4+ with Perfluorinated Aryl Thiolates featuring Unusual Molecular Structures
AD Mironova, MA Mikhaylov… - European Journal of …, 2022 - Wiley Online Library
A series of six novel cluster complexes [M6I8 (SArf) 6] 2−(M= Mo or W; SArf= p‐SC6F4‐
C6F5, p‐SC6F4Cl, or p‐SC6F4CF3) was prepared by exchange reactions between …
C6F5, p‐SC6F4Cl, or p‐SC6F4CF3) was prepared by exchange reactions between …
Synthesis and Structure of Trinuclear W3S4 Clusters Bearing Aminophosphine Ligands and Their Reactivity toward Halides and Pseudohalides
TF Beltran, JA Pino-Chamorro… - Inorganic …, 2015 - ACS Publications
The aminophosphine ligand (2-aminoethyl) diphenylphosphine (edpp) has been
coordinated to the W3 (μ-S)(μ-S) 3 cluster unit to afford trimetallic complex [W3S4Br3 (edpp) …
coordinated to the W3 (μ-S)(μ-S) 3 cluster unit to afford trimetallic complex [W3S4Br3 (edpp) …
Influence of the Ligand Alkyl Chain Length on the Solubility, Aqueous Speciation, and Kinetics of Substitution Reactions of Water-Soluble M3S4 (M = Mo, W) Clusters …
Water-soluble [M3S4X3 (dhbupe) 3]+ diphosphino complexes (dhbupe= 1, 2-bis (bis
(hydroxybutyl) phosphino) ethane), 1+(M= Mo, X= Cl) and 2+(M= W; X= Br), have been …
(hydroxybutyl) phosphino) ethane), 1+(M= Mo, X= Cl) and 2+(M= W; X= Br), have been …
Hemilability of phosphine-thioether ligands coordinated to trinuclear Mo 3 S 4 cluster and its effect on hydrogenation catalysis
AL Gushchin, NY Shmelev, SF Malysheva… - New Journal of …, 2018 - pubs.rsc.org
Ligand-exchange reactions of [Mo3S4 (tu) 8 (H2O)] Cl4· 4H2O (tu= thiourea) with
(PhCH2CH2) 2PCH2CH2SR ligands, where R= Ph (PS1), pentyl (PS2) or Pr (PS3), afford …
(PhCH2CH2) 2PCH2CH2SR ligands, where R= Ph (PS1), pentyl (PS2) or Pr (PS3), afford …
Reaction schemes that are easily confused with a reversible first–order reaction
ABSTRACT A detailed kinetic analysis of two schemes, one involving coupled consecutive
processes and another featuring the simultaneous association reaction and decay of a …
processes and another featuring the simultaneous association reaction and decay of a …
Kinetic studies on the oxidation of oxyhemoglobin by biologically active iron thiosemicarbazone complexes: relevance to iron-chelator-induced methemoglobinemia
MT Basha, C Rodríguez, DR Richardson… - JBIC Journal of …, 2014 - Springer
The oxidation of oxyhemoglobin to methemoglobin has been found to be facilitated by low
molecular weight iron (III) thiosemicarbazone complexes. This deleterious reaction, which …
molecular weight iron (III) thiosemicarbazone complexes. This deleterious reaction, which …
Interaction of hydrophobic tungsten cluster complexes with a phospholipid bilayer
IS Dovydenko, YA Laricheva… - The Journal of …, 2019 - ACS Publications
Nanoconstructions composed of lipid vesicles and inorganic units (nanoparticles, metal
complexes) arouse much interest across materials science and nanotechnology as hybrid …
complexes) arouse much interest across materials science and nanotechnology as hybrid …