Mechanical properties and peculiarities of molecular crystals

WM Awad, DW Davies, D Kitagawa… - Chemical Society …, 2023 - pubs.rsc.org
In the last century, molecular crystals functioned predominantly as a means for determining
the molecular structures via X-ray diffraction, albeit as the century came to a close the …

Enlightening materials with photoswitches

A Goulet‐Hanssens, F Eisenreich… - Advanced Materials, 2020 - Wiley Online Library
Incorporating molecular photoswitches into various materials provides unique opportunities
for controlling their properties and functions with high spatiotemporal resolution using …

Leveraging crystalline and amorphous states of a metal‐organic complex for transformation of the photosalient effect and positive‐negative photochromism

YJ Ma, G Xiao, X Fang, T Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
Uncovering differences between crystalline and amorphous states in molecular solids would
both promote the understanding of their structure–property relationships, as well as inform …

The rise of the dynamic crystals

P Naumov, DP Karothu, E Ahmed… - Journal of the …, 2020 - ACS Publications
The anticipated shift in the focal point of interest of solid-state chemists, crystal engineers,
and crystallographers from structure to properties to function parallels the need to apply our …

Organic radical ferroelectric crystals with martensitic phase transition

N Zhang, W Sun, Y Zhang, HH Jiang, RG Xiong… - Nature …, 2023 - nature.com
Organic martensitic compounds are an emerging type of smart material with intriguing
physical properties including thermosalient effect, ferroelasticity, and shape memory effect …

Single-crystal-to-single-crystal [2+ 2] photocycloaddition reaction in a photosalient one-Dimensional coordination polymer of Pb (II)

BB Rath, JJ Vittal - Journal of the American Chemical Society, 2020 - ACS Publications
In a remarkable example, we report a one-dimensional coordination polymer (CP) of Pb (II)
showing photosalient (PS) properties triggered by [2+ 2] cycloaddition of olefinic ligands …

Phase Transition‐Promoted Rapid Photomechanical Motions of Single Crystals of a Triene Coordination Polymer

C Cao, XR Xue, QY Li, MJ Zhang… - Angewandte Chemie …, 2023 - Wiley Online Library
Molecular crystals with the ability to transform light energy into macroscopic mechanical
motions are a promising class of materials with potential applications in actuating and …

Control of photomechanical crystal twisting by illumination direction

D Kitagawa, H Tsujioka, F Tong, X Dong… - Journal of the …, 2018 - ACS Publications
Photomechanical molecular crystals have been investigated as mesoscopic photoactuators.
Here, we report how the photomechanical twisting of 1, 2-bis (2-methyl-5-phenyl-3-thienyl) …

Recent advances of dynamic molecular crystals with light-triggered macro-movements

B Zhou, D Yan - Applied Physics Reviews, 2021 - pubs.aip.org
Dynamic molecular crystals showing light-triggered macro-movements have attracted great
attention due to their unique ability for light–force conversion. These molecular crystals are …

Halogen effect in photomechanical molecular crystals

J Zhong, J Sun, K Ye, R Lu - Journal of Materials Chemistry C, 2023 - pubs.rsc.org
Inspired by sophisticated and intelligent biological systems, various smart actuations
triggered by physical or chemical stimuli have been developed. Photomechanical materials …