Photoswitchable arylazopyrazole-based ruthenium (II) arene complexes

K Ghebreyessus, SM Cooper Jr - Organometallics, 2017 - ACS Publications
A new family of donor-functionalized photoswitchable arylazopyrazole-based ligands (3–5)
was synthesized and characterized. The new ligands have been employed to prepare a …

Reaction of platinum (II) derivatives with 1-hydroxyalkyl-3, 5-dimethylpyrazole ligands. Cleavage of the N (pz) C (sp3) bond. X-ray crystal structure of cis-[PtCl2 (HL2) …

A Boixassa, J Pons, X Solans, M Font-Bardia… - Inorganica chimica acta, 2003 - Elsevier
The reactions of 1-hydroxymethyl-3, 5-dimethylpyrazole (HL1) and 1-(2-hydroxyethyl)-3, 5-
dimethylpyrazole (HL2) with several platinum starting materials ([PtCl2 (CH3CN) 2], cis-and …

Synthesis and Characterization of Pyrazolyl‐Functionalized Imidazolium‐Based Ionic Liquids and Hemilabile (Carbene) palladium (II) Complex Catalyzed Heck …

R Wang, Z Zeng, B Twamley, MM Piekarski… - 2007 - Wiley Online Library
Abstract Neat reactions of 1‐(pyrazolylmethyl) imidazole with an excess of alkyl or
polyfluoroalkyl halides at 100° C followed by subsequent metathetical reactions with LiN …

Synthesis, spectroscopic properties and structural characterisation of Pd (II) and Pt (II) complexes with 1, 3, 5-pyrazole derived ligands. Rotation around the metal–N …

V Montoya, J Pons, X Solans, M Font-Bardia… - Inorganica chimica acta, 2005 - Elsevier
Reactions of ligands 1-ethyl-5-methyl-3-phenyl-1H-pyrazole (L1) and 5-methyl-1-octyl-3-
phenyl-1H-pyrazole (L2) with [PdCl2 (CH3CN) 2 and K2PtCl4 gave complexes trans-[MCl2 …

Synthesis of New PdII Complexes Containing a Thioether‐Pyrazole Hemilabile Ligand − Structural Analysis by 1H, 13C NMR Spectroscopy and Crystal Structure of [PdCl(bdtp …

J García‐Antón, J Pons, X Solans… - European Journal of …, 2003 - Wiley Online Library
Abstract Treatment of the ligand 1, 5‐bis (3, 5‐dimethyl‐1‐pyrazolyl)‐3‐thiapentane (bdtp)
with [PdCl2 (CH3CN) 2] led to a [PdCl2 (bdtp)] complex. Subsequent treatment of this …

Pyrazolic palladium compounds containing alcohol functionality: hindered rotation around Pd N bond

A Boixassa, J Pons, A Virgili, X Solans… - Inorganica chimica …, 2002 - Elsevier
Reactions of the ligands 1-hydroxymethyl-3, 5-dimethylpyrazole (HL1), 1-(2-hydroxyethyl)-3,
5-dimethylpyrazole (HL2) and 1-(3-hydroxypropyl)-3, 5-dimethylpyrazole (HL3) with [PdCl2 …

Synthesis, X-ray crystal structure, and NMR characterisation of thiolate-bridged dinuclear Ni (II), Pd (II) and Pt (II) complexes of didentate ligands with NS-donor set

J Garcı́a-Antón, J Pons, X Solans, M Font-Bardia… - Inorganica chimica …, 2003 - Elsevier
Thiolate-bridged dinuclear nickel (II), palladium (II) and platinum (II) complexes with N-(2-
mercaptoethyl)-3, 5-dimethylpyrazole (Hmed),[MCl (med)] 2 (M= Ni (1), Pd (2), Pt (3)), have …

Synthesis of a New Potentially Hemilabile Ligand: 1‐[2‐(Diphenylphosphanyl) ethyl]‐3, 5‐dimethylpyrazole, and Comparison of Its Bonding Properties with the …

G Esquius, J Pons, R Yáñez, J Ros… - European Journal of …, 2002 - Wiley Online Library
Abstract The new ligand 1‐[2‐(diphenylphosphanyl) ethyl]‐3, 5‐dimethylpyrazole (2) has
been prepared by the reaction of 1‐(chloroethyl)‐3, 5‐dimethylpyrazole and PPh2Li. The …

Synthesis of New PdII Complexes Containing Thioether−Pyrazole Hemilabile Ligands − Structural Analysis by 1H and 13C NMR Spectroscopy and Crystal Structures of [PdCl2(bddo)] and …

J García‐Antón, J Pons, X Solans… - European Journal of …, 2002 - Wiley Online Library
Abstract Treatment of the ligands 1, 6‐bis (3, 5‐dimethyl‐1‐pyrazolyl)‐2, 5‐dithiahexane
(bddh), 1, 7‐bis (3, 5‐dimethyl‐1‐pyrazolyl)‐2, 6‐dithiaheptane (bddhp), 1, 8‐bis (3, 5 …

Reactivity of [PdCl (μ-med)] 2 with monodentate or bidentate ligands. Structure of the dinuclear complexes [Pd (μ-med)(PPh3)] 2 (BF4) 2 and [Pd (μ-med)(bpy)] 2 (BF4) …

J Garcı́a-Antón, J Pons, X Solans, M Font-Bardia… - Inorganica chimica …, 2004 - Elsevier
Treatment of the ligand N-(2-mercaptoethyl)-3, 5-dimethylpyrazole with [Pd (CH3COO) 2] 3
and reaction of [PdCl (μ-med)] 2 with pyridine (py) or triphenylphosphine (PPh3) in the …