Tropospheric halogen chemistry: Sources, cycling, and impacts

WR Simpson, SS Brown, A Saiz-Lopez… - Chemical …, 2015 - ACS Publications
In the past 40 years, atmospheric chemists have come to realize that halogens exert a
powerful influence on the chemical composition of the troposphere and through that …

Reactive halogen chemistry in the troposphere

A Saiz-Lopez, R von Glasow - Chemical Society Reviews, 2012 - pubs.rsc.org
Halogen chemistry is well known for ozone destruction in the stratosphere, however reactive
halogens also play an important role in the chemistry of the troposphere. In the last two …

Multi axis differential optical absorption spectroscopy (MAX-DOAS)

G Hönninger, C Von Friedeburg… - … Chemistry and Physics, 2004 - acp.copernicus.org
Multi Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) in the atmosphere is a
novel measurement technique that represents a significant advance on the well-established …

Role of the ocean in the global mercury cycle

RP Mason, GR Sheu - Global biogeochemical cycles, 2002 - Wiley Online Library
Air‐sea exchange of mercury (Hg) is a critical part of the global Hg cycle as it determines, to
a large degree, the response time of the biosphere to changes in mercury inputs. Recent …

Halogens and their role in polar boundary-layer ozone depletion

WR Simpson, R Von Glasow, K Riedel… - Atmospheric …, 2007 - acp.copernicus.org
During springtime in the polar regions, unique photochemistry converts inert halide salt ions
(eg Br−) into reactive halogen species (eg Br atoms and BrO) that deplete ozone in the …

Vibrational spectroscopy of aqueous sodium halide solutions and air− liquid interfaces: Observation of increased interfacial depth

D Liu, G Ma, LM Levering, HC Allen - The Journal of Physical …, 2004 - ACS Publications
Air− aqueous sodium halide solution interfaces are examined using vibrational sum
frequency generation spectroscopy. Raman and ATR-FTIR (attenuated total reflection …

The tropospheric chemistry of sea salt: A molecular-level view of the chemistry of NaCl and NaBr

BJ Finlayson-Pitts - Chemical reviews, 2003 - ACS Publications
The chemistry of the troposphere entails a complex combination of gaseous, aqueous, and
surface processes involving a wide variety of compounds, both organic and inorganic. 1 …

Antarctic springtime depletion of atmospheric mercury

R Ebinghaus, HH Kock, C Temme… - … science & technology, 2002 - ACS Publications
Unlike other heavy metals that are inherently associated with atmospheric aerosols, mercury
in ambient air exists predominantly in the gaseous elemental form. Because of its prolonged …

On temperate sources of bromoform and other reactive organic bromine gases

LJ Carpenter, PS Liss - Journal of Geophysical Research …, 2000 - Wiley Online Library
Current estimates of annual bromoform production by temperate marine algae
underestimate, by at least an order of magnitude, the flux required to sustain atmospheric …

New ultraviolet absorption cross-sections of BrO at atmospheric temperatures measured by time-windowing Fourier transform spectroscopy

OC Fleischmann, M Hartmann, JP Burrows… - … of Photochemistry and …, 2004 - Elsevier
The UV absorption cross-section spectra of the atmospherically important radical BrO have
been determined using the recently developed technique of time-windowing Fourier …