Employing phenols and phenol derivatives as electrophiles for cross-coupling reactions has
numerous advantages over commonly used aryl halides in terms of environmental …

The formation of C–aryl bonds has been the focus of intensive research over the last
decades for the construction of complex molecules from simple, readily available feedstocks …

Cross-coupling reactions, which were discovered almost 50 years ago, are widely used in
both industry and academia. Even though cross-coupling reactions now represent mature …

Over the last decade, substantial research has led to the introduction of an impressive
number of efficient procedures which allow the selective construction of C C bonds by …

Conspectus Arene synthesis has been revolutionized by the invention of catalytic cross-
coupling reactions, wherein aryl halides can be coupled with organometallic and organic …

In 1979, the seminal work of Wenkert set the standards for the utilization of aryl and vinyl
ethers as coupling partners via C–O bond-cleavage. Although the topic remained dormant …

In den vergangenen zehn Jahren wurde eine beeindruckende Zahl an Verfahren entwickelt,
die den selektiven Aufbau von C‐C‐Bindungen über die direkte Verknüpfung von zwei …

The Ni-catalyzed cross-coupling of aryl ethers is a powerful synthetic tool to transform widely
available phenol derivatives into functionalized aromatic molecules. Recent theoretical and …

Two protocols for the nickel-catalyzed cross-coupling of aryl fluorides with aryl boronic
esters have been developed. The first employs metal fluoride cocatalysts, such as ZrF4 and …

Acting as an environmentally benign synthetic tool, the cross-coupling reactions with aryl
ethers via C–O bond activation have attracted broad interest. However, the …