Polymers without petrochemicals: sustainable routes to conventional monomers

G Hayes, M Laurel, D MacKinnon, T Zhao… - Chemical …, 2022 - ACS Publications
Access to a wide range of plastic materials has been rationalized by the increased demand
from growing populations and the development of high-throughput production systems …

N-Heterocyclic Carbenes in Materials Chemistry

CA Smith, MR Narouz, PA Lummis, I Singh… - Chemical …, 2019 - ACS Publications
N-Heterocyclic carbenes (NHCs) have become one of the most widely studied class of
ligands in molecular chemistry and have found applications in fields as varied as catalysis …

Exploiting hexafluoroisopropanol (HFIP) in Lewis and Brønsted acid-catalyzed reactions

V Pozhydaiev, M Power, V Gandon, J Moran… - Chemical …, 2020 - pubs.rsc.org
Hexafluoroisopropanol (HFIP) is a solvent with unique properties that has recently gained
attention for promoting a wide range of challenging chemical reactions. It was initially …

Chemically recyclable polymers: a circular economy approach to sustainability

M Hong, EYX Chen - Green Chemistry, 2017 - pubs.rsc.org
The current practices in the generation and disposal of synthetic polymers are largely
unsustainable. As part of the solution, the development of biodegradable polymers, which …

Covalent modifiers: A chemical perspective on the reactivity of α, β-unsaturated carbonyls with thiols via hetero-Michael addition reactions

PA Jackson, JC Widen, DA Harki… - Journal of medicinal …, 2017 - ACS Publications
Although Michael acceptors display a potent and broad spectrum of bioactivity, they have
largely been ignored in drug discovery because of their presumed indiscriminate reactivity …

Toward infinitely recyclable plastics derived from renewable cyclic esters

X Tang, EYX Chen - Chem, 2019 - cell.com
Plastics, used in countless consumer products that our daily lives depend on, have become
indispensable materials essential for modern life and the global economy. At the same time …

Polymerization of polar monomers mediated by main-group Lewis acid–base pairs

M Hong, J Chen, EYX Chen - Chemical reviews, 2018 - ACS Publications
The development of new or more sustainable, active, efficient, controlled, and selective
polymerization reactions or processes continues to be crucial for the synthesis of important …

Catalytic asymmetric synthesis of butenolides and butyrolactones

B Mao, M Fañanás-Mastral, BL Feringa - Chemical reviews, 2017 - ACS Publications
γ-Butenolides, γ-butyrolactones, and derivatives, especially in enantiomerically pure form,
constitute the structural core of numerous natural products which display an impressive …

Catalytic Enantioselective C H Functionalization of Alcohols by Redox‐Triggered Carbonyl Addition: Borrowing Hydrogen, Returning Carbon

JM Ketcham, I Shin, TP Montgomery… - Angewandte Chemie …, 2014 - Wiley Online Library
The use of alcohols and unsaturated reactants for the redox‐triggered generation of
nucleophile–electrophile pairs represents a broad, new approach to carbonyl addition …

Transition‐Metal‐Catalyzed Hydrogen‐Transfer Annulations: Access to Heterocyclic Scaffolds

A Nandakumar, SP Midya, VG Landge… - Angewandte Chemie …, 2015 - Wiley Online Library
The ability of hydrogen‐transfer transition‐metal catalysts, which enable increasingly rapid
access to important structural scaffolds from simple starting materials, has led to a plethora …