Polymers without petrochemicals: sustainable routes to conventional monomers
G Hayes, M Laurel, D MacKinnon, T Zhao… - Chemical …, 2022 - ACS Publications
Access to a wide range of plastic materials has been rationalized by the increased demand
from growing populations and the development of high-throughput production systems …
from growing populations and the development of high-throughput production systems …
N-Heterocyclic Carbenes in Materials Chemistry
N-Heterocyclic carbenes (NHCs) have become one of the most widely studied class of
ligands in molecular chemistry and have found applications in fields as varied as catalysis …
ligands in molecular chemistry and have found applications in fields as varied as catalysis …
Exploiting hexafluoroisopropanol (HFIP) in Lewis and Brønsted acid-catalyzed reactions
Hexafluoroisopropanol (HFIP) is a solvent with unique properties that has recently gained
attention for promoting a wide range of challenging chemical reactions. It was initially …
attention for promoting a wide range of challenging chemical reactions. It was initially …
Chemically recyclable polymers: a circular economy approach to sustainability
The current practices in the generation and disposal of synthetic polymers are largely
unsustainable. As part of the solution, the development of biodegradable polymers, which …
unsustainable. As part of the solution, the development of biodegradable polymers, which …
Covalent modifiers: A chemical perspective on the reactivity of α, β-unsaturated carbonyls with thiols via hetero-Michael addition reactions
PA Jackson, JC Widen, DA Harki… - Journal of medicinal …, 2017 - ACS Publications
Although Michael acceptors display a potent and broad spectrum of bioactivity, they have
largely been ignored in drug discovery because of their presumed indiscriminate reactivity …
largely been ignored in drug discovery because of their presumed indiscriminate reactivity …
Toward infinitely recyclable plastics derived from renewable cyclic esters
Plastics, used in countless consumer products that our daily lives depend on, have become
indispensable materials essential for modern life and the global economy. At the same time …
indispensable materials essential for modern life and the global economy. At the same time …
Polymerization of polar monomers mediated by main-group Lewis acid–base pairs
The development of new or more sustainable, active, efficient, controlled, and selective
polymerization reactions or processes continues to be crucial for the synthesis of important …
polymerization reactions or processes continues to be crucial for the synthesis of important …
Catalytic asymmetric synthesis of butenolides and butyrolactones
B Mao, M Fañanás-Mastral, BL Feringa - Chemical reviews, 2017 - ACS Publications
γ-Butenolides, γ-butyrolactones, and derivatives, especially in enantiomerically pure form,
constitute the structural core of numerous natural products which display an impressive …
constitute the structural core of numerous natural products which display an impressive …
Catalytic Enantioselective C H Functionalization of Alcohols by Redox‐Triggered Carbonyl Addition: Borrowing Hydrogen, Returning Carbon
JM Ketcham, I Shin, TP Montgomery… - Angewandte Chemie …, 2014 - Wiley Online Library
The use of alcohols and unsaturated reactants for the redox‐triggered generation of
nucleophile–electrophile pairs represents a broad, new approach to carbonyl addition …
nucleophile–electrophile pairs represents a broad, new approach to carbonyl addition …
Transition‐Metal‐Catalyzed Hydrogen‐Transfer Annulations: Access to Heterocyclic Scaffolds
A Nandakumar, SP Midya, VG Landge… - Angewandte Chemie …, 2015 - Wiley Online Library
The ability of hydrogen‐transfer transition‐metal catalysts, which enable increasingly rapid
access to important structural scaffolds from simple starting materials, has led to a plethora …
access to important structural scaffolds from simple starting materials, has led to a plethora …