Supramolecular polymerization through kinetic pathway control and living chain growth

M Wehner, F Würthner - Nature Reviews Chemistry, 2020 - nature.com
Supramolecular polymers exhibit fascinating structures, and their properties, and thus
applications, depend both on the strength and dynamics of the non-covalent bonds and on …

Emerging applications for living crystallization-driven self-assembly

L MacFarlane, C Zhao, J Cai, H Qiu, I Manners - Chemical Science, 2021 - pubs.rsc.org
The use of crystallization as a tool to control the self-assembly of polymeric and molecular
amphiphiles in solution is attracting growing attention for the creation of non-spherical …

Concepts, fabrication methods and applications of living crystallization-driven self-assembly of block copolymers

S Ganda, MH Stenzel - Progress in Polymer Science, 2020 - Elsevier
Living crystallization-driven self-assembly (CDSA) has emerged as a technique that is able
to perform solution phase self-assembly of semi-crystalline block copolymers in a controlled …

Metallopolymers for advanced sustainable applications

Y Wang, D Astruc, AS Abd-El-Aziz - Chemical Society Reviews, 2019 - pubs.rsc.org
Since the development of metallopolymers, there has been tremendous interest in the
applications of this type of materials. The interest in these materials stems from their …

Scalable and uniform length-tunable biodegradable block copolymer nanofibers with a polycarbonate core via living polymerization-induced crystallization-driven self …

CE Ellis, JD Garcia-Hernandez… - Journal of the American …, 2022 - ACS Publications
Uniform 1D block copolymer (BCP) nanofibers prepared by the seeded-growth approach
termed living crystallization-driven self-assembly (CDSA) offer promising potential for …

A guide to supramolecular polymerizations

M Hartlieb, EDH Mansfield, S Perrier - Polymer Chemistry, 2020 - pubs.rsc.org
Supramolecular polymers or fibers are non-covalent assemblies of unimeric building blocks
connected by secondary interactions such as hydrogen bonds or π–π interactions. Such …

A block supramolecular polymer and its kinetically enhanced stability

SH Jung, D Bochicchio, GM Pavan… - Journal of the …, 2018 - ACS Publications
Biomolecular systems serve as an inspiration for the creation of multicomponent synthetic
supramolecular systems that can be utilized to develop functional materials with complexity …

Tweaking a BODIPY Spherical Self‐Assembly to 2D Supramolecular Polymers Facilitates Excited‐State Cascade Energy Transfer

G Das, S Cherumukkil, A Padmakumar… - Angewandte Chemie …, 2021 - Wiley Online Library
Excited state properties such as emission, exciton transport, electron transfer, etc., are
strongly dependent on the shape, size and molecular arrangement of chromophore based …

Unraveling concomitant packing polymorphism in metallosupramolecular polymers

A Langenstroer, KK Kartha, Y Dorca… - Journal of the …, 2019 - ACS Publications
The phenomenon of polymorphism is ubiquitous in biological systems and has also been
observed in various types of self-assembled materials in solution and in the solid state. In …

Uniform two-dimensional square assemblies from conjugated block copolymers driven by π–π interactions with controllable sizes

L Han, M Wang, X Jia, W Chen, H Qian, F He - Nature Communications, 2018 - nature.com
Abstract Two-dimensional (2-D) micro-and nano-architectures are attractive because of their
unique properties. However, the formation of 2-D supramolecular highly symmetrical …