Organic peroxy radicals (often abbreviated RO2) play a central role in the chemistry of the
Earth's lower atmosphere. Formed in the atmospheric oxidation of essentially every organic …

Advanced low-temperature combustion concepts that rely on compression ignition have
placed new technological demands on the modeling of low-temperature oxidation in general …

The chemistry of the atmosphere encompasses a vast number of reactions acting on a
plethora of intermediates. These reactions, occurring sequentially and in parallel, give rise to …

We propose, and quantify from first principles, two novel HOx-regenerating unimolecular
reactions in isoprene oxidation, which are estimated to yield in pristine tropical forest …

The Leuven isoprene mechanism, proposed earlier to aid in rationalizing the unexpectedly
high hydroxyl radical (OH) concentrations in isoprene-rich, low-nitric-oxide (NO) regions …

We describe a nearly explicit chemical mechanism for isoprene photooxidation guided by
chamber studies that include time-resolved observation of an extensive suite of volatile …

We present a detailed budget of formic and acetic acids, two of the most abundant trace
gases in the atmosphere. Our bottom-up estimate of the global source of formic and acetic …

Alkenes formed, during the refining of crude oil, by cracking the heavier fractions are present
in transportation fuels in significant amounts, up to as much as 15–20% in gasoline …

Kinetics provides the fundamental parameters for elucidating sources and sinks of key
atmospheric species and for atmospheric modeling more generally. Obtaining quantitative …

A large data set of rate coefficients for H migration in peroxy radicals is presented and
supplemented with literature data to derive a structure–activity relationship (SAR) for the title …